Zinc
About Zinc

Zinc is one of a few metals that were widely used by human societies in alloys long before they were recognized as metals themselves. The earliest brasses, alloys of copper and small percentages of zinc, first produced as early as several millennia BCE, likely resulted from the accidental smelting of zinc-rich copper ores. There is evidence that by the eighth century BCE, the special properties of metals smelted from such ores was recognized, and thus the ore was highly valued and sought after.
Later, starting in the first century BCE, brass was produced by heating copper ore and zinc ore together, producing a zinc vapor that reacted with the copper. At this time, brass became widely used in coinage and military equipment, and the methods for producing it spread around the world. By the 14th century in India and 17th century in China, the metallic form of zinc was finally produced deliberately, and a variety of European chemists and alchemists worked with the metal, but discovery of zinc as an element is generally credited to German chemist Andreas Marggraf for his extensive work in 1746, which documented his ability to obtain metallic zinc from a number of zinc compounds.
In modern times, zinc continues to be used as an alloy metal. Brass alloys are more corrosion resistant than copper and more workable than zinc alone or the other common copper alloy, bronze. They are additionally notable for their acoustic properties, which lend them to use in musical instruments. Brass also retains some of the antimicrobial properties of copper, and therefore is used for commonly touched objects in hospitals, including doorknobs and surfaces. Another alloy, "nickel silver," contains nickel, copper, and zinc, and is used decoratively and for many musical instruments that are silver in color. There are also many majority-zinc alloys tailored to specific uses, with small amounts of additives used to impart key qualities. Zinc-aluminum, for example, has a lower melting point and lower viscosity than zinc, making it more suitable for casting of small and intricate shapes. Zinc sheet metals are produced using small amounts of titanium and copper, which make a resulting alloy less brittle than zinc that therefore can be roll formed or bent.
As important as zinc alloys have been throughout history and still are today, in modern times zinc’s largest use is in galvanizing other metals, usually iron or steel, to protect them against corrosion. Galvanization is simply the application of a thin coating of zinc to a metal surface through any of several methods. Initially, the top of this layer reacts with the atmosphere to produce zinc carbonate, which protects all the underlying metal from corrosion. When the zinc layer is scratched down to the underlying metal, however, zinc still protects the underlying metal, now by acting as a sacrificial anode. This same property is exploited when zinc is used as the sacrificial anode in cathodic protection of buried pipelines or submerged iron components of a ship. Zinc also serves as an anode in alkaline batteries, zinc-carbon batteries, silver-zinc batteries, and zinc-air fuel cells, and as a cathode in silver oxide batteries.
Dozens of zinc compounds find use in everyday products such as deodorants, cosmetics, sunscreens, anti-dandruff shampoos, and dietary supplements. Some zinc compounds find use in organic synthesis or industrial chemistry: notably, zinc oxide has long been used as a catalyst in the vulcanization of rubber. Additionally, compounds of zinc with oxygen, sulfur, selenium, or tellurium are all II-VI semiconductors with properties that recommend them for a variety of optoelectronic applications, including light-emitting diodes (LEDs), laser diodes, and solar cells. Zinc sulfide, zinc selenide, and zinc telluride all are used as infrared or near-infrared optical materials, and doped versions of each compound exist with other useful properties such as scintillation. Zinc may also serve as a component the ternary semiconductors cadmium zinc telluride and mercury zinc telluride, which are useful for similar applications, but additionally have band gaps that can be easily tuned by altering the precise composition of the material.
Zinc is the fourth most commonly used metal, behind only iron, aluminum, and copper. It is mined primarily from zinc sulfide deposits, which are generally roasted to produce zinc oxide and then processed to the metal through pyrometallurgy or electrowinning. Most of the zinc used annually is newly mined, but about thirty percent is recycled.
Products
Compounds
- Ammonium Zinc Sulfate Hydrate
- Bismuth Cobalt Zinc Oxide
- Copper Aluminum Zinc Oxide
- Lithium Zinc Oxide
- Lithopone
- Magnesium Zinc Titanate
- Mercury(II) Zinc Thiocyanate
- Molybdenum Zinc Oxide
- Osmium Zinc Iodide
- Pentazinc Chromate Octahydroxide
- Silver Zinc Oxide
- Silver Zinc Zeolite
- Zinc Acetate
- Zinc Acetate, Basic
- Zinc Acetate Dihydrate
- Zinc Acetate Solution
- Zinc Ammonium Chloride
- Zinc Arsenate
- Zinc Borate
- Zinc Borate Pentahydrate
- Zinc Borohydride
- Zinc Bromate
- Zinc Bromide
- Zinc Bromide Dihydrate
- Zinc Bromide Hydrate
- Zinc Bromide, Ultra Dry
- Zinc Carbide
- Zinc Carbide Foam
- Zinc Carbonate Basic
- Zinc Carbonate
- Zinc Chloride
- Zinc Chloride, Ultra Dry
- Zinc Chloride Solution
- Zinc Chloride Hydroxide Monohydrate
- Zinc Chromate
- Zinc Cyanide
- Zinc Dichromate Trihydrate
- Zinc Dihydrogen Phosphate
- Zinc Fluoride
- Zinc Fluoride Tetrahydrate
- Zinc Fluoroborate
- Zinc Formate
- Zinc Formate Dihydrate
- Zinc Hexacyanocobaltate
- Zinc Hexafluorosilicate Hydrate
- Zinc Hydroxide
- Zinc Hydroxystannate
- Zinc Iodate
- Zinc Iodide
- Zinc Iodide, Ultra Dry
- Zinc Iron Oxide
- Zinc Laurate
- Zinc Metaborate
- Zinc Molybdate
- Zinc Niobate
- Zinc Nitrate
- Zinc Nitrate Hexahydrate
- Zinc Nitrate Solution
- Zinc Nitrate Tetrahydrate
- Zinc Nitride
- Zinc Oxalate
- Zinc Oxalate Dihydrate
- Zinc Oxide
- Zinc Perchlorate Hexahydrate
- Zinc Permanganate
- Zinc Peroxide
- Zinc Phosphate
- Zinc Phosphate Dihydrate
- Zinc Phosphate Hydrate
- Zinc Phosphate Tetrahydrate
- Zinc Phthalocyanine
- Zinc Selenite
- Zinc Silicate
- Zinc Stearate
- Zinc Sulfate
- Zinc Sulfate Heptahydrate
- Zinc Sulfate Hydrate
- Zinc Sulfate Monohydrate
- Zinc Sulfate Solution
- Zinc Sulfite
- Zinc Sulfite Dihydrate
- Zinc Tetrafluoroborate Hydrate
- Zinc Thiocyanate
- Zinc Titanate ZnTiO3
- Zinc(IV) Titanate Zn2TiO4
- Zinc Trifluoroacetate Hydrate
- Zinc Tungstate
- Zinc Zirconate
Metallic Forms
- Zinc Balls
- Zinc Bands
- Zinc Bars
- Zinc Blocks
- Zinc Chunk
- Zinc Coil
- Zinc Concentrate
- Zinc Cubes
- Zinc Cut Wire Shot
- Zinc Crucibles
- Zinc Cylinder
- Zinc Disc
- Zinc Electrodes
- Zinc Flake
- Zinc Flanges
- Zinc Foam
- Zinc Foil
- Zinc Granules
- Zinc Honeycomb
- Zinc Ingot
- Zinc Lump
- Zinc Mesh
- Zinc Metal
- Zinc Mossy
- Zinc Nanoscale Foil
- Zinc Particles
- Zinc Parts
- Zinc Pellets
- Zinc Pieces
- Zinc Plate
- Zinc Powder
- Zinc Puck
- Zinc Ribbon
- Zinc Rings
- Zinc Rod
- Zinc Samples
- Zinc Shaving
- Zinc Sheet
- Zinc Shot
- Zinc Single Crystal
- Zinc Sleeves
- Zinc Slugs
- Zinc Specimens
- Zinc Spheres
- Zinc Sponge
- Zinc Spring
- Zinc Strip
- Zinc Tape
- Zinc Tubes
- Zinc Wafer
- Zinc Wire
- Zinc Wool
Alloys
- Aluminum 7075 Alloy
- Brass Electrodes
- Bismuth Zinc Alloy
- Cadmium Zinc Alloy
- Copper Aluminum Zinc Alloy
- Copper Iron Zinc Alloy
- Copper Nickel Zinc Alloy
- Copper Zinc Alloy
- Copper Zinc Alloy Flakes
- Copper Zinc Alloy Particles
- Copper Zinc Alloy Powder
- Copper Zinc Aluminum Nickel Alloy
- Copper Zinc Silver Alloy
- Copper Zinc Tin Alloy
- Gold Zinc Slugs
- Indium Zinc Alloy
- Indium Zinc Foil
- Magnesium Aluminum Zinc Alloy
- Magnesium Aluminum Zinc Foil
- Magnesium Zinc Zirconium Alloy
- Nickel Zinc Copper Titanium Alloy
- Silver Cadmium Zinc Copper Alloy Particles
- Silver Cadmium Zinc Copper Alloy Powder
- Silver Copper Zinc Alloy
- Silver Copper Zinc Manganese Nickel Alloy
- Silver Copper Zinc Nickel Alloy
- Silver Copper Zinc Tin Alloy
- Silver Zinc Alloy
- Silver Zinc Nickel Alloy
- Tin Bismuth Zinc Alloy
- Tin Bismuth Zinc Powder
- Tin Silver Zinc Alloy
- Tin Zinc Alloy
- Zinc Aluminum Alloy
- Zinc Copper Alloy
- Zinc Copper Titanium Alloy
- Zinc Magnesium Alloy
- Zinc Nickel Alloy
Oxide Forms
Organometallics
- 2,3,7,8,12,13,17,18-Octaethyl-21H,23H-porphine Zinc(II)
- 2-Chlorophenylzinc Iodide Solution
- 2-Fluorophenylzinc Iodide Solution
- 2-Methylimidazole Zinc Salt
- 2-Propylzinc Bromide Solution
- [3,4-Toluenedithiolato(2-)]zinc Hydrate
- 3-Butenylzinc Bromide
- 4-Diethylamino-2-Methylbenzenediazonium Chloride, Zinc Chloride Double Salt
- 5,10,15,20-Tetraphenyl-21H,23H-porphine Zinc
- 8-Hydroxyquinoline Zinc
- Acridine Orange hemi(zinc chloride) Salt
- Bis(2,2,6,6-tetramethyl-3,5-heptanedionato)zinc(II)
- Bis[2-(2-benzothiazolyl)phenolato]zinc(II)
- Bis(2-methyl-8-hydroxyquinolinato)zinc
- Bis(pentafluorophenyl)zinc
- Dichloro(N,N,N',N'-tetramethylethylenediamine)zinc
- Diethylzinc
- Diisopropyl Zinc Solution
- Dimethylzinc
- Diphenylzinc
- Fumaric Acid Monoethyl Ester Zinc Salt
- Meldola's Blue
- Methyl Green, Zinc Chloride Salt
- n-Propylzinc Bromide Solution
- p-Diazo-N,N-diethyl-m-toluidine hemi(zinc chloride) salt
- Zinc 1,2,3,4,8,9,10,11,15,16,17,18,22,23,24,25-hexadecafluoro-29H,31H-phthalocyanine
- Zinc 1,4,8,11,15,18,22,25-octabutoxy-29H,31H-phthalocyanine
- Zinc 2,11,20,29-tetra-tert-butyl-2,3-naphthalocyanine
- Zinc 2,3,9,10,16,17,23,24-octakis(octyloxy)-29H,31H-phthalocyanine
- Zinc 2,9,16,23-tetra-tert-butyl-29H,31H-phthalocyanine
- Zinc 2,9,16,23-tetrakis(phenylthio)-29H,31H-phthalocyanine
- Zinc 2-Ethylhexanoate
- Zinc 2-Ethylhexanoate Solution
- Zinc 2-Methoxyethoxide
- Zinc 29H,31H-tetrabenzo[b,g,l,q]porphine
- Zinc 3,5-di-tert-butylsalicylate
- Zinc 5,10,15,20-tetra(4-pyridyl)-21H,23H-porphine
- Zinc 5,10,15,20-tetra(4-pyridyl)-21H,23H-porphine Tetrakis(methochloride)
- Zinc Acetylacetonate
- Zinc Acetylacetonate Hydrate
- Zinc Acrylate
- Zinc Benzenesulfinate Dihydrate
- Zinc Bis[bis(trimethylsilyl)amide]
- Zinc bis(trifluoromethylsulfonyl)imide
- Zinc Caprylate
- Zinc Chloride Tetrahydrofuran Complex
- Zinc Chlorothiophenolate
- Zinc Citrate Dihydrate
- Zinc Cyclohexanebutyrate Dihydrate
- Zinc(II) Dibenzyldithiocarbamate
- Zinc Dibutyldithiocarbamate
- Zinc Diethyldithiocarbamate
- Zinc Dimethyldithiocarbamate
- Zinc Hexafluoroacetylacetonate Dihydrate
- Zinc Isopropoxide
- Zinc Methionine
- Zinc Methacrylate
- Zinc Methoxide
- Zinc N-Ethyl-N-phenyldithiocarbamate
- Zinc Naphthenate
- Zinc Neodecanoate
- Zinc Octoate
- Zinc Oleate
- Zinc p-toluenesulfonate Hydrate
- Zinc Phthalocyanine
- Zinc Picolinate
- Zinc Protoporphyrin IX
- Zinc Pyrithione
- Zinc Tartrate
- Zinc tert-Butoxide
- Zinc(II) Tetranitrophthalocyanine
- Zinc Trifluoromethanesulfonate
- Zinc(II) Trifluoromethanesulfinate
- Zinc Undecylenate
Nanomaterials
- Aluminum-doped Zinc Oxide Nanoparticle Dispersion
- Aluminum-doped Zinc Oxide Nanoparticle Ink
- Aluminum-doped Zinc Oxide Nanoparticles
- Bismuth Cobalt Zinc Oxide Nanoparticle Dispersion
- Bismuth Cobalt Zinc Oxide Nanoparticles
- Cadmium Selenide/Zinc Sulfide Quantum Dots
- CdSeTe/ZnS Quantum Dots
- Cobalt Iron Zinc Oxide Nanoparticle Dispersion
- Copper Zinc Nanoparticles
- Copper Zinc Nanoparticle Dispersion
- Copper Zinc Iron Oxide Nanoparticle Dispersion
- Copper Zinc Iron Oxide Nanoparticles
- Copper-Zinc Alloy Nanoprisms
- Copper Zinc Alloy Nanoparticles
- Devarda's Alloy Nanoparticles
- Gallium-Doped Zinc Oxide (GZO) Nanoparticle Dispersion
- Gallium-doped Zinc Oxide Nanoparticles
- InP/ZnS Quantum Dots
- Magnesium-Doped Zinc Oxide Quantum Dots
- Magnesium Zinc Iron Oxide Nanoparticle Dispersion
- Magnesium Zinc Iron Oxide Nanoparticles
- Mn doped ZnO Quantum Dots
- Manganese Zinc Iron Oxide Nanoparticle Dispersion
- Mn/ZnSe Quantum Dots
- Nickel Zinc Iron Oxide Nanoparticle Dispersion
- Nickel Zinc Iron Oxide Nanoparticles
- Zinc Cadmium Selenide/Zinc Sulfide Quantum Dots
- Zinc Iron Oxide Nanoparticle Dispersion
- Zinc Iron Oxide Nanoparticles
- Zinc Nanoparticles
- Zinc Nanoparticle Dispersion
- Zinc Nanorods
- Zinc Oxide Nanoparticles
- Zinc Oxide Nanowire
- Zinc Selenide/Zinc Sulfide Quantum Dots
- Zinc Titanate Nanoparticles
- ZnCdSeS alloyed Quantum Dots
- ZnCuInS/ZnS Quantum Dots
- ZnO Quantum Dots
Semiconductor & Optical
- Aluminum Zinc Oxide AZO
- Antimony Zinc Oxide
- Copper Zinc Tin Selenide
- Copper Zinc Tin Sulfide
- Gallium doped Zinc Oxide GZO
- Gadolinium doped Zinc Oxide Gd:ZnO
- Indium Gallium Zinc Oxide IGZO
- Indium Zinc Oxide
- Zinc Antimonide ZnSb
- Zinc Antimonide Zn4Sb3
- Zinc Antimonide Concentrate
- Zinc Antimonide Dust
- Zinc Antimonide Grain
- Zinc Antimonide Granules
- Zinc Antimonide Powder
- Zinc Antimonide Precipitate
- Zinc Antimonide Residue
- Zinc Antimonide Shaving
- Zinc(IV) Arsenide ZnAs2
- Zinc(II) Arsenide Zn3As2
- Zinc Cadmium Telluride Granule
- Zinc Cadmium Telluride Lump
- Zinc Cadmium Telluride Powder
- Zinc Diphosphide
- Zinc Germanium Phosphide Granules
- Zinc Germanium Phosphide Powder
- Zinc Germanium Phosphide Lump
- Zinc Indium Telluride Granules
- Zinc Indium Telluride Lump
- Zinc Indium Telluride Powder
- Zinc Manganese Telluride
- Zinc Oxide/Gallium Oxide
- Zinc Oxide/Magnesium Oxide
- Zinc Phosphide
- Zinc Selenide
- Zinc Selenide Beam Splitters
- Zinc Selenide Lenses
- Zinc Selenide Pieces
- Zinc Selenide Prisms
- Zinc Selenide Windows
- Zinc Silicate, Manganese-doped
- Zinc Sulfide
- Zinc Sulfide Crystal
- Zinc Sulfide Granules
- Zinc Sulfide Pieces
- Zinc Sulfide Powder
- Zinc Sulfide Tablets
- Zinc Sulfide Wafer
- Zinc Sulfide Windows
- Zinc Telluride
- Zinc Tin Antimonide
- Zinc Tin Phosphide Granules
- Zinc Tin Phosphide Lump
- Zinc Tin Phosphide Powder
- ZnCdSe
- ZnCdTe
- ZnMgSSe
- ZnS:Cu,Al Phosphor
- ZnSSe
Sputtering Targets
- Aluminum Copper Magnesium Chromium Zinc Sputtering Target
- Aluminum Copper Magnesium Chromium Zinc Rotatable Sputtering Target
- Antimony doped Zinc Tin Sputtering Target
- AZO Sputtering Target
- AZO Rotatable Sputtering Target
- Bismuth Zinc Niobate Sputtering Target
- Cadmium Zinc Sulfide Sputtering Target
- Copper Iron Zinc Alloy Sputtering Target
- Copper Nickel Zinc Alloy Sputtering Target
- Copper Zinc Sputtering Target
- Copper Zinc Tin Sputtering Target
- Germanium Zinc Alloy Sputtering Target
- GZO Sputtering Target
- Indium Gallium Zinc Alloy Sputtering Target
- Indium Gallium Zinc Oxide IGZO Sputtering Target
- IZO Sputtering Target
- Lithium Zinc Oxide Sputtering Target
- Magnesium Aluminum Zinc Alloy Sputtering Target
- Magnesium Zinc Oxide Sputtering Target
- Silver-Zinc Oxide Sputtering Target
- Tin Zinc Sputtering Target
- Zinc Aluminium Rotatable Sputtering Target
- Zinc Aluminum Oxide Rotatable Sputtering Target
- Zinc Aluminum Oxide Sputtering Target
- Zinc Aluminum Sputtering Target
- Zinc Antimonide Sputtering Target
- Zinc Arsenide Sputtering Target
- Zinc Bismuth Telluride Sputtering Target
- Zinc Cadmium Telluride Sputtering Target
- Zinc Carbonate Sputtering Target
- Zinc Copper Sputtering Target
- Zinc-doped Gallium Phosphide Sputtering Target
- Zinc Fluoride Sputtering Target
- Zinc Gallium Oxide Sputtering Target
- Zinc Indium Telluride Sputtering Target
- Zinc Iridium Oxide Sputtering Target
- Zinc Iron Oxide Sputtering Target
- Zinc Magnesium Sputtering Target
- Zinc Manganese Oxide Sputtering Target
- Zinc Nitride Sputtering Target
- Zinc Oxide/Phosphorus Oxide Sputtering Target
- Zinc Oxide Rotatable Sputtering Target
- Zinc Oxide Sputtering Target
- Zinc Oxide, Scandia-doped Sputtering Target
- Zinc Oxide/Sodium Sputtering Target
- Zinc Oxide/Zinc Sulfide Sputtering Target
- Zinc Phosphate Sputtering Target
- Zinc Phosphide Sputtering Target
- Zinc Rotatable Sputtering Target
- Zinc Selenide Sputtering Target
- Zinc Silicon Sputtering Target
- Zinc Sputtering Target
- Zinc Sulfide Sputtering Target
- Zinc Telluride Sputtering Target
- Zinc Tin Oxide Sputtering Target
- Zinc Vanadate Sputtering Target
Isotopes
Zinc has unusual electrical, thermal, optical, and solid-state properties that have not been fully investigated. Zinc metal is employed to form numerous alloys with other metals. Brass, nickel silver, commercial bronze, soft solder, and aluminum solder are some of the more important zinc alloys. Zinc is used to produce die castings which are used extensively by the automotive, electrical, and hardware industries. Zinc is also used to galvanize other metals such as iron to prevent corrosion. Zinc oxide is widely used in the manufacture of paints, rubber products, cosmetics, pharmaceuticals, floor coverings, plastics, printing inks, soap, storage batteries, textiles, and electrical equipment. Zinc sulfide is used in making luminous dials, X-ray and TV screens, and fluorescent lights.
The chloride and chromate are also important compounds. Zinc is available as metal and compounds with purities from 99% to 99.999% (ACS grade to ultra-high purity). Elemental or metallic forms include pellets, rod, wire and granules for evaporation source material purposes. Zinc nanoparticles and nanopowders provide ultra-high surface area. Zinc oxide is available in powder and dense pellet form for such uses as optical coating and thin film applications. Oxides tend to be insoluble. Fluorides are another insoluble form for uses in which oxygen is undesirable such as metallurgy, chemical and physical vapor deposition and in some optical coating. Zinc is also available in soluble forms including chlorides, nitrates and acetates. These compounds can be manufactured as solutions at specified stoichiometries.
Zinc Properties
Zinc is a Block D, Group 12, Period 4 element. The number of electrons in each of zinc's shells is 2, 8, 18, 2, and its electron configuration is [Ar] 3d10 4s2. The zinc atom has a radius of 133.5.pm and its Van der Waals radius is 139.pm. In its elemental form, CAS 7440-66-6, zinc has a silver-gray appearance.
It is brittle at ordinary temperatures but malleable at 100 °C to 150 °C.
It is a fair conductor of electricity, and burns in air at high red producing white clouds of the oxide. Zinc is mined from sulfidic ore deposits. The most common zinc ore is sphalerite (zinc blende), a zinc sulfide mineral. It is is the 24th most abundant element in the earth's crust and the fourth most common metal in use (after iron, aluminum, and copper). Metallic zinc was first isolated from a variety of zinc compounds by Andreas Marggraf in 1746. The element name zinc originates from the German word "zin" meaning tin.
General Properties
Symbol: | Zn |
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Atomic Number: | 30 |
Atomic Weight: | 65.38 |
Element Category: | transition metal |
Group, Period, Block: | 12, 4, d |
Color: | bluish pale gray/ bluish silver |
Other Names: | Zincum, Zink, Zinco |
Physical Properties
Melting Point: | 419.53 °C, 787.15 °F, 692.68 K |
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Boiling Point: | 907 °C, 1665 °F, 1180 K |
Density: | 7.14 g·cm3 |
Liquid Density @ Melting Point: | 6.57 g·cm3 |
Density @ 20°C: | 7.14 g/cm3 |
Density of Solid: | 7140 kg·m3 |
Specific Heat: | 0.0928 Cal/g/K @ 25 °C |
Superconductivity Temperature: | 0.85 [or -272.3 °C (-458.1 °F)] K |
Triple Point: | 692.65 K, 0.065 kPa |
Critical Point: | N/A |
Heat of Fusion (kJ·mol-1): | 6.67 |
Heat of Vaporization (kJ·mol-1): | 114.2 |
Heat of Atomization (kJ·mol-1): | 130.181 |
Thermal Conductivity: | 1.16 W/cm/K @ 298.2 K |
Thermal Expansion: | (25 °C) 30.2 µm·m-1·K-1 |
Electrical Resistivity: | (20 °C) 59.0 nΩ·m |
Tensile Strength: | N/A |
Molar Heat Capacity: | 25.470 J·mol-1·K-1 |
Young's Modulus: | 108 GPa |
Shear Modulus: | 43 GPa |
Bulk Modulus: | 70 GPa |
Poisson Ratio: | 0.25 |
Mohs Hardness: | 2.5 |
Vickers Hardness: | N/A |
Brinell Hardness: | 412 MPa |
Speed of Sound: | (r.t.) (rolled) 3850 m·s-1 |
Pauling Electronegativity: | 1.65 |
Sanderson Electronegativity: | 2.23 |
Allred Rochow Electronegativity: | 1.66 |
Mulliken-Jaffe Electronegativity: | 1.65 (sp orbital) |
Allen Electronegativity: | N/A |
Pauling Electropositivity: | 2.35 |
Reflectivity (%): | 80 |
Refractive Index: | 1.00205 |
Chemical Properties
Electrons: | 30 |
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Protons: | 30 |
Neutrons: | 35 |
Electron Configuration: | [Ar] 3d10 4s2 |
Atomic Radius: | 134 pm |
Atomic Radius, non-bonded (Å): | 2.01 |
Covalent Radius: | 122±4 pm |
Covalent Radius (Å): | 1.2 |
Van der Waals Radius: | 139 pm |
Oxidation States: | +2, +1, 0 (amphoteric oxide) |
Phase: | Solid |
Crystal Structure: | hexagonal close-packed |
Magnetic Ordering: | diamagnetic |
Electron Affinity (kJ·mol-1) | Not stable |
1st Ionization Energy: | 906.41 kJ·mol-1 |
2nd Ionization Energy: | 1733.31 kJ·mol-1 |
3rd Ionization Energy: | 3832.71 kJ·mol-1 |
Identifiers
CAS Number: | 7440-66-6 |
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EC Number: | 231-175-3 |
MDL Number: | MFCD00011291 |
Beilstein Number: | N/A |
SMILES Identifier: | [Zn] |
InChI Identifier: | InChI=1S/Zn |
InChI Key: | HCHKCACWOHOZIP-UHFFFAOYSA-N |
PubChem CID: | 23994 |
ChemSpider ID: | 22430 |
Abundance
Earth - Total: | 74 ppm |
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Mercury - Total: | 12.1 ppm |
Venus - Total: | 82 ppm |
Earth - Seawater (Oceans), ppb by weight: | 5 |
Earth - Seawater (Oceans), ppb by atoms: | 0.47 |
Earth - Crust (Crustal Rocks), ppb by weight: | 79000 |
Earth - Crust (Crustal Rocks), ppb by atoms: | 25000 |
Sun - Total, ppb by weight: | 2000 |
Sun - Total, ppb by atoms: | 30 |
Stream, ppb by weight: | 10 |
Stream, ppb by atoms: | 0.2 |
Meterorite (Carbonaceous), ppb by weight: | 180000 |
Meterorite (Carbonaceous), ppb by atoms: | 44000 |
Typical Human Body, ppb by weight: | 33000 |
Typical Human Body, ppb by atom: | 3200 |
Universe, ppb by weight: | 300 |
Universe, ppb by atom: | 6 |
History
Discovered By: | Indian metallurgists |
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Discovery Date: | Prior to 1000 BC |
First Isolation: | Andreas Sigismund Marggraf (1746) |
Health, Safety & Transportation Information for Zinc
Zinc is considered non-toxic in moderate doses but can cause nausea if taken in excess. Safety data for Zinc and its compounds can vary widely depending on the form. For potential hazard information, toxicity, and road, sea and air transportation limitations, such as DOT Hazard Class, DOT Number, EU Number, NFPA Health rating and RTECS Class, please see the specific material or compound referenced in the Products tab. The below information applies to elemental (metallic) Zinc.
Safety Data | |
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Signal Word | Danger |
Hazard Statements | H251-H261 |
Hazard Codes | F,N |
Risk Codes | 15-17-50/53 |
Safety Precautions | 43-46-60-61 |
RTECS Number | ZG8600000 |
Transport Information | UN 1436 4.3/PG 2 |
WGK Germany | nwg |
Globally Harmonized System of Classification and Labelling (GHS) | ![]() |
Review and Print SDS for Zinc Metal
SAFETY DATA SHEET
SECTION 1. IDENTIFICATION
Product Name: Zinc Metal
Product Number: All applicable American Elements product codes, e.g. ZN-M-02, ZN-M-03, ZN-M-04, ZN-M-05, ZN-M-06
CAS #: 7440-66-6
Relevant identified uses of the substance: Scientific research and development
Supplier details:
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Emergency telephone number:
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International +1 703-527-3887
SECTION 2. HAZARDS IDENTIFICATION
Classification of the substance or mixture
Classification according to Regulation (EC) No 1272/2008
The substance is not classified as hazardous to health or the environment according to the CLP regulation.
Hazards not otherwise classified
No information known.
Label elements
Labelling according to Regulation (EC) No 1272/2008
Not applicable
Hazard pictograms
Not applicable
Signal word
Not applicable
Hazard statements
Not applicable
WHMIS classification
Not controlled
Classification system
HMIS ratings (scale 0-4)
(Hazardous Materials Identification System)
HEALTH
FIRE
REACTIVITY
0
0
0
Health (acute effects) = 0
Flammability = 0
Physical Hazard = 0
Other hazards
Results of PBT and vPvB assessment
PBT: Not applicable.
vPvB: Not applicable.
SECTION 3. COMPOSITION/INFORMATION ON INGREDIENTS
Chemical characterization: Substances
CAS# Description:
7440-66-6 Zinc
Identification number(s):
EC number: 231-175-3
SECTION 4. FIRST AID MEASURES
Description of first aid measures
General information
No special measures required.
After inhalation
Seek medical treatment in case of complaints.
After skin contact
Generally the product does not irritate the skin.
After eye contact
Rinse opened eye for several minutes under running water. If symptoms persist, consult a doctor.
After swallowing
If symptoms persist consult doctor.
Information for doctor
Most important symptoms and effects, both acute and delayed
No further relevant information available.
Indication of any immediate medical attention and special treatment needed
No further relevant information available.
SECTION 5. FIREFIGHTING MEASURES
Extinguishing media
Suitable extinguishing agents
Special powder for metal fires. Do not use water.
For safety reasons unsuitable extinguishing agents
Water
Special hazards arising from the substance or mixture
If this product is involved in a fire, the following can be released:
Metal oxide fume
Advice for firefighters
Protective equipment:
No special measures required
SECTION 6. ACCIDENTAL RELEASE MEASURES
Personal precautions, protective equipment and emergency procedures
Not required.
Environmental precautions:
Do not allow material to be released to the environment without proper governmental permits.
Methods and material for containment and cleaning up:
Pick up mechanically.
Prevention of secondary hazards:
No special measures required.
Reference to other sections
See Section 7 for information on safe handling
See Section 8 for information on personal protection equipment.
See Section 13 for disposal information.
SECTION 7. HANDLING AND STORAGE
Handling
Precautions for safe handling
Keep container tightly sealed.
Store in cool, dry place in tightly closed containers.
Information about protection against explosions and fires:
No special measures required.
Conditions for safe storage, including any incompatibilities
Storage
Requirements to be met by storerooms and receptacles:
No special requirements.
Information about storage in one common storage facility:
Not required.
Further information about storage conditions:
Keep container tightly sealed.
Store in cool, dry conditions in well sealed containers.
Specific end use(s)
No further relevant information available.
SECTION 8. EXPOSURE CONTROLS/PERSONAL PROTECTION
Additional information about design of technical systems:
No further data; see section 7.
Control parameters
Components with limit values that require monitoring at the workplace:
The product does not contain any relevant quantities of materials with critical values that have to be monitored at the workplace.
Additional information: No data
Exposure controls
Personal protective equipment
General protective and hygienic measures
The usual precautionary measures for handling chemicals should be followed.
Maintain an ergonomically appropriate working environment.
Breathing equipment: Not required.
Protection of hands: Not required.
Penetration time of glove material (in minutes): Not determined
Eye protection: Safety glasses
Body protection: Protective work clothing.
SECTION 9. PHYSICAL AND CHEMICAL PROPERTIES
Information on basic physical and chemical properties
General Information
Appearance:
Form: Solid in various forms
Color: Grey
Odor: Odorless
Odor threshold: Not determined.
pH-value: Not applicable.
Change in condition
Melting point/Melting range: 419.5 °C (787 °F)
Boiling point/Boiling range: 907 °C (1665 °F)
Sublimation temperature / start: Not determined
Flammability (solid, gaseous): Not determined.
Ignition temperature: Not determined
Decomposition temperature: Not determined
Auto igniting: Not determined.
Danger of explosion: Not determined.
Explosion limits:
Lower: Not determined
Upper: Not determined
Vapor pressure: Not applicable.
Density at 20 °C (68 °F): 7.14 g/cm³ (59.583 lbs/gal)
Relative density: Not determined.
Vapor density: Not applicable.
Evaporation rate: Not applicable.
Solubility in / Miscibility with Water: Insoluble
Partition coefficient (n-octanol/water): Not determined.
Viscosity:
dynamic: Not applicable.
kinematic: Not applicable.
Other information
No further relevant information available.
SECTION 10. STABILITY AND REACTIVITY
Reactivity
No information known.
Chemical stability
Stable under recommended storage conditions.
Thermal decomposition / conditions to be avoided:
Decomposition will not occur if used and
stored according to specifications.
Possibility of hazardous reactions
No dangerous reactions known
Conditions to avoid
No further relevant information available.
Incompatible materials:
No information known.
Hazardous decomposition products:
Metal oxide fume
SECTION 11. TOXICOLOGICAL INFORMATION
Information on toxicological effects
Acute toxicity:
The Registry of Toxic Effects of Chemical Substances (RTECS) contains acute toxicity data for components in this product.
LD/LC50 values that are relevant for classification: No data
Skin irritation or corrosion: No irritant effect.
Eye irritation or corrosion: No irritant effect.
Sensitization: No sensitizing effects known.
Germ cell mutagenicity: No effects known.
Carcinogenicity:
EPA-I: Data are inadequate for an assessment of human carcinogenic potential.
The Registry of Toxic Effects of Chemical Substances (RTECS) contains tumorigenic and/or carc inogenic and/or neoplastic data for this substance.
Reproductive toxicity: No effects known.
Specific target organ system toxicity - repeated exposure: No effects known.
Specific target organ system toxicity - single exposure: No effects known.
Aspiration hazard: No effects known.
Subacute to chronic toxicity:
The Registry of Toxic Effects of Chemical Substances (RTECS) contains multiple dose toxicity data for this substance.
Additional toxicological information:
To the best of our knowledge the acute and chronic toxicity of this substance is not fully known.
Carcinogenic categories
OSHA-Ca (Occupational Safety & Health Administration)
Substance is not listed.
SECTION 12. ECOLOGICAL INFORMATION
Toxicity
Aquatic toxicity:
No further relevant information available.
Persistence and degradability
No further relevant information available.
Bioaccumulative potential
No further relevant information available.
Mobility in soil
No further relevant information available.
Additional ecological information:
General notes:
Do not allow material to be released to the environment without proper governmental permits.
Avoid transfer into the environment.
Results of PBT and vPvB assessment
PBT: Not applicable.
vPvB: Not applicable.
Other adverse effects
No further relevant information available.
SECTION 13. DISPOSAL CONSIDERATIONS
Waste treatment methods
Recommendation
Consult state, local or national regulations to ensure proper disposal.
Uncleaned packagings:
Recommendation:
Disposal must be made according to official regulations.
SECTION 14. TRANSPORT INFORMATION
UN-Number
DOT, ADN, IMDG, IATA
Not applicable
UN proper shipping name
DOT, ADN, IMDG, IATA
Not applicable
Transport hazard class(es)
DOT, ADR, ADN, IMDG, IATA
Class
Not applicable
Packing group
DOT, IMDG, IATA
Not applicable
Environmental hazards:
Not applicable.
Special precautions for user
Not applicable.
Transport in bulk according to Annex II of MARPOL73/78 and the IBC Code
Not applicable.
Transport/Additional information:
DOT
Marine Pollutant (DOT):
No
UN "Model Regulation":
-
SECTION 15. REGULATORY INFORMATION
Safety, health and environmental regulations/legislation specific for the substance or mixture
National regulations
All components of this product are listed in the U.S. Environmental Protection Agency Toxic Substances Control Act Chemical substance Inventory.
All components of this product are listed on the Canadian Domestic Substances List (DSL).
SARA Section 313 (specific toxic chemical listings)
7440-66-6 Zinc
California Proposition 65
Prop 65 - Chemicals known to cause cancer
Substance is not listed.
Prop 65 - Developmental toxicity
Substance is not listed.
Prop 65 - Developmental toxicity, female
Substance is not listed.
Prop 65 - Developmental toxicity, male
Substance is not listed.
Information about limitation of use:
For use only by technically qualified individuals.
This product is subject to the reporting requirements of section 313 of the Emergency Planning and Community Right to Know Act of 1986 and 40CFR372.
Other regulations, limitations and prohibitive regulations
Substance of Very High Concern (SVHC) according to the REACH Regulations (EC) No. 1907/2006.
Substance is not listed.
The conditions of restrictions according to Article 67 and Annex XVII of the Regulation (EC) No 1907/2006 (REACH) for the manufacturing, placing on the market and use must be observed.
Substance is not listed.
Annex XIV of the REACH Regulations (requiring Authorisation for use)
Substance is not listed.
Chemical safety assessment:
A Chemical Safety Assessment has not been carried out.
16. OTHER INFORMATION
Safety Data Sheet according to Regulation (EC) No. 1907/2006 (REACH). The above information is believed to be correct but does not purport to be all inclusive and shall be used only as a guide. The information in this document is based on the present state of our knowledge and is applicable to the product with regard to appropriate safety precautions. It does not represent any guarantee of the properties of the product. American Elements shall not be held liable for any damage resulting from handling or from contact with the above product. See reverse side of invoice or packing slip for additional terms and conditions of sale. COPYRIGHT 1997-2016 AMERICAN ELEMENTS. LICENSED GRANTED TO MAKE UNLIMITED PAPER COPIES FOR INTERNAL USE ONLY.
Zinc Isotopes
Zinc has 5 stable isotopes: 64Zn, 66Zn, 67Zn, 68Zn, and 70Zn.
Nuclide | Isotopic Mass | Half-Life | Mode of Decay | Nuclear Spin | Magnetic Moment | Binding Energy (MeV) | Natural Abundance (% by atom) |
---|---|---|---|---|---|---|---|
54Zn | 53.99295(43)# | N/A | 2p to 52Ni | 0+ | N/A | 410.04 | - |
55Zn | 54.98398(27)# | 20# ms [>1.6 µs] | 2p to 53Ni; ß+ to 55Cu | 5/2-# | N/A | 426.5 | - |
56Zn | 55.97238(28)# | 36(10) ms | ß+ to 56Cu | 0+ | N/A | 444.83 | - |
57Zn | 56.96479(11)# | 38(4) ms | ß+ + p to 56Ni; ß+ to 57Cu | 7/2-# | N/A | 460.36 | - |
58Zn | 57.95459(5) | 84(9) ms | ß+ + p to 57Ni; ß+ to 58Cu | 0+ | N/A | 477.76 | - |
59Zn | 58.94926(4) | 182.0(18) ms | ß+ to 59Cu; ß+ + p to 58Ni | 3/2- | N/A | 490.5 | - |
60Zn | 59.941827(11) | 2.38(5) min | EC to 60Cu | 0+ | N/A | 506.03 | - |
61Zn | 60.939511(17) | 89.1(2) s | EC to 61Cu | 3/2- | N/A | 515.97 | - |
62Zn | 61.934330(11) | 9.186(13) h | EC to 62Cu | 0+ | N/A | 528.71 | - |
63Zn | 62.9332116(17) | 38.47(5) min | EC to 63Cu | 3/2- | -0.28164 | 537.72 | - |
64Zn | 63.9291422(7) | Observationally Stable | - | 0+ | N/A | 549.52 | 48.63 |
65Zn | 64.9292410(7) | 243.66(9) d | EC to 65Cu | 5/2- | 0.769 | 557.6 | - |
66Zn | 65.9260334(10) | STABLE | - | 0+ | N/A | 568.47 | 27.9 |
67Zn | 66.9271273(10) | STABLE | - | 5/2- | 0.875479 | 575.62 | 4.1 |
68Zn | 67.9248442(10) | STABLE | - | 0+ | N/A | 586.49 | 18.75 |
69Zn | 68.9265503(10) | 56.4(9) min | ß- to 69Ga | 1/2- | N/A | 592.71 | - |
70Zn | 69.9253193(21) | Observationally Stable | - | 0+ | N/A | 601.72 | 0.62 |
71Zn | 70.927722(11) | 2.45(10) min | ß- to 71Ga | 1/2- | N/A | 607.94 | - |
72Zn | 71.926858(7) | 46.5(1) h | ß- to 72Ga | 0+ | N/A | 616.95 | - |
73Zn | 72.92978(4) | 23.5(10) s | ß- to 73Ga | (1/2)- | N/A | 622.23 | - |
74Zn | 73.92946(5) | 95.6(12) s | ß- to 74Ga | 0+ | N/A | 630.31 | - |
75Zn | 74.93294(8) | 10.2(2) s | ß- to 75Ga | (7/2+)# | N/A | 635.59 | - |
76Zn | 75.93329(9) | 5.7(3) s | ß- to 76Ga | 0+ | N/A | 642.74 | - |
77Zn | 76.93696(13) | 2.08(5) s | ß- to 77Ga | (7/2+)# | N/A | 648.02 | - |
78Zn | 77.93844(10) | 1.47(15) s | ß- to 78Ga | 0+ | N/A | 654.24 | - |
79Zn | 78.94265(28)# | 0.995(19) s | ß- to 79Ga; ß- + n to 78Ga | (9/2+) | N/A | 658.59 | - |
80Zn | 79.94434(18) | 545(16) ms | ß- to 80Ga; ß- + n to 79Ga | 0+ | N/A | 664.81 | - |
81Zn | 80.95048(32)# | 290(50) ms | ß- to 81Ga; ß- + n to 80Ga | 5/2+# | N/A | 667.29 | - |
82Zn | 81.95442(54)# | 100# ms [>300 ns] | ß- to 82Ga | 0+ | N/A | 671.65 | - |
83Zn | 82.96103(54)# | 80# ms [>300 ns] | Unknown | 5/2+# | N/A | 673.2 | - |