Tungsten
About Tungsten
Though tin-rich minerals were plentiful in Germany’s Erzgebirge mountains during the Middle Ages, smelting the metal proved difficult due to the presence of substance that produced a heavy slag and leached tin away from the final yield. Frustrated metallurgists called this unwanted tin-“devouring” mineral wolf ram (wolf’s drool, cream, or soot, depending on translation), a pejorative term from which the mineral wolframite takes its name. In 1781, Carl Wilhelm Scheele predicted that the acid he had obtained by reducing a mineral named tungsten (from the Swedish tung sten, meaning “heavy stone”) contained a new element; two years later, when Spanish chemists José and Fausto Elhuyar obtained the same acid from the mineral wolframite, they succeeded in isolating the new element which they named wolfram. Confusingly, this element also came to be referred to as tungsten, while the mineral formally known as tungsten took on the name scheelite. “Wolfram” and “tungsten” remained co-listed in the nomenclature recommendations of the IUPAC (International Union of Pure and Applied Chemistry) up until 2005, when tungsten became the transition metal’s only officially recognized name. Tungsten retains the elemental symbol of W, though, and is still referred to as wolfram by some chemists and scientists around the world.
Tungsten is a hard, extremely dense metal ranging in appearance from steel gray to silvery white. True to its name, tungsten is indeed heavy, but by far its most outstanding characteristic is its resistance to heat. High melting points are characteristic of the refractory metals (a group that also includes niobium, tantalum, rhenium, and molybdenum), but tungsten’s melting point of 3410 ± 20°C is the single highest of any metal--higher than the temperatures at which metals like aluminum would vaporize--and its boiling point of 5900°C is roughly equal to the temperature of the sun’s surface. Of all metals, tungsten also exhibits the highest tensile strength, lowest coefficient of linear thermal expansion, and lowest vapor pressure at elevated temperatures. Tungsten metal is also electrically conductive and possesses outstanding mechanical damping capability, extremely high resistance to corrosion, high moduli of elasticity and compression, excellent creep resistance, and the ability to absorb x-ray and gamma ray radiation.
Natural tungsten is composed of five isotopes with half-lives so long they are considered essentially stable. It is the heaviest element with a known biological function (used by some enzymes), and as such is not harmful to humans and animals in quantities typically encountered in the environment. The aforementioned scheelite and wolframite are the two main mineral sources of tungsten; other less common minerals include ferberite and hübnerite. Despite its assets, raw tungsten contains impurities that make it extremely brittle and difficult to machine; producing ultra-high purity tungsten increases its malleability and ductility while retaining its thermal stability, as does alloying it with other metals such as rhenium. Commercially, tungsten is typically produced in the form of ammonium paratungstate via a multi-step process of solvent extraction and crystallization of sodium tungstate extracted from concentrated ores. Recycling of tungsten scrap is also a significant source of industrial tungsten. Tungsten metal can be obtained by heating tungsten oxide with aluminum or by passing hydrogen gas over hot tungstic acid.
Its high melting point made tungsten an attractive material for use in early incandescent lamps, but overcoming the difficulty of drawing it into flexible wires was a challenge. In 1909 GE researcher William D. Coolidge developed a revolutionary process for producing ductile tungsten filaments for use in light bulbs and high-precision x-ray tubes. Coolidge’s colleague Irving Langmuir further advanced lighting technology by discovering that coating a tungsten filament with a single layer of thorium atoms and shaping it into a coil greatly enhanced performance, while using a non-reactive gas like argon or nitrogen and prevented the tungsten from overheating, opening the door for the wide use of tungsten filaments in television tubes and cathode ray tubes. Other consumer applications for tungsten include components of High Intensity Discharge (HID) and vacuum metallized reflector lamps, pigments for ceramic glazes and enamels, dyes, inks, and metal-to-glass seals due to its similar expansion rate to borosilicate glass.
Tungsten has applications in numerous industries and fields of study. The metal and its alloys are the choice material for high temperature, high pressure environments. Combining the metal with nickel, cobalt, iron, molybdenum, tantalum, or rhenium yields uniquely dense and oxidation-resistant alloys and superalloys that are used in aircraft engines, turbine blades, furnace components, heating filaments, evaporation coils, melting crucibles, high voltage circuit breakers, balancing weights, vibration dampers, load-resistant crankshafts, base plates and heat spreaders, plasma spray gun nozzles, and magnetrons for microwave ovens. It is suitable as a nontoxic alternative to lead in ammunition and is frequently added to stainless steel to increase its strength. Typical tungsten-based precursors for catalysts and reagents include ammonium metatungstate, tungstic acid and ammonium paratungstate for use in lubrication, mineral separation and deNOx of emissions from chemical and power plants; tungsten oxide is a common petrochemical additive to decrease emissions and increase efficiency of hydrocarbon fuels. Tungsten carbide is an extremely dense material found in industrial machinery, cutting tools, abrasives, cermets, sports equipment, and some jewelry. “Cemented carbides” are produced by combining tungsten carbide with a nickel, copper, or iron via powder metallurgy or liquid sintering to create a flexible, high strength material that is one of the most versatile for engineering and tooling and is commonly employed as substrates and support for synthetic diamond or boron nitride cutting tips and drill bits. Tungsten electrodes doped with thorium, cerium, or other rare earth oxides are employed in gas tungsten arc welding (GTAW), also known as tungsten inert gas (TIG) or wolfram inert gas (WIG) welding. An effective neutron reflector, tungsten is frequently employed in nuclear reactors, collimators, and for x-ray and gamma ray shielding; the first imaging equipment involved x-ray bombardment of a tungsten target.
Tungsten compounds play a role in advanced optoelectronics, thermosolar cells, and other cutting-edge high technology applications. Thin films of tungsten oxide can be used as a component of smart windows; cadmium tungstate is a phosphor material used in light-emitting diodes. Tungsten diselenide (WSe2) and tungsten disulfide (WS2) belong to a group known as transition metal dichalcogenides (TMDs or TMDCs) that have gained attention in recent years many for their ability to form two-dimensional 1-atom thick monolayers similar to graphene but with a larger band gap. Tungsten diselenide has been used to create an n-type field-effect-transistor (FET), demonstrating the potential for future low-power and high-performance tungsten-based integrated circuits.
Products
Compounds
- 12-Wolframosilicic Acid
- Aluminum Tungstate
- Ammonium Metatungstate Hydrate
- Ammonium Paratungstate
- Ammonium Tetrathiotungstate
- Ammonium Tungstate
- Ammonium Tungstate Pentahydrate
- Barium Borotungstate
- Barium Calcium Tungsten Oxide
- Barium Tungstate
- Barium Strontium Tungsten Oxide
- Barium Yttrium Tungsten Oxide
- Bismuth Tungstate
- Cadmium Borotungstate
- Cadmium Tungstate
- Calcium Tungstate
- Cerium Tungstate
- Cerium Tungsten Oxide
- Cesium Tungstate
- Cobalt Tungstate
- Copper Tungstate
- Europium Tungstate
- Iron Tungstate
- Lanthanum Tungstate La2O9W2
- Lanthanum Tungstate La2O12W3
- Lead Tungstate
- Lithium Tungstate
- Magnesium Tungstate
- Manganese Tungstate
- Mercury(I) Tungstate
- Mercury(II) Tungstate
- Nickel Tungstate
- Niobium Tungsten Oxide
- Phosphotungstic Acid Anhydrous
- Phosphotungstic Acid Hydrate
- Potassium Tungstate
- Rubidium Tungstate
- Silicotungstic Acid
- Silver Tungstate
- Sodium Metatungstate Hydrate
- Sodium Phosphotungstate Tribasic Hydrate
- Sodium Phosphotungstate Hydrate
- Sodium Polytungstate
- Sodium Polytungstate Solution
- Sodium Tungstate
- Sodium Tungsten Oxide Dihydrate
- Strontium Tungstate
- Tungsten Boride WB
- Tungsten Boride W2B
- Tungsten Boride W2B5
- Tungsten(II) Bromide
- Tungsten(V) Bromide
- Tungsten Carbide
- Tungsten Carbide Copper Alloy
- Tungsten Carbide Powder
- Tungsten Carbide-Silver
- Tungsten Carbide W2C
- Tungsten Diboride
- Tungsten Dichloride
- Tungsten(VI) Dichloride Dioxide
- Tungsten Dichloride Solution
- Tungsten(IV) Fluoride WF4
- Tungsten(VI) Fluoride WF6
- Tungsten Hexachloride
- Tungsten(II) Iodide
- Tungsten(III) Iodide
- Tungsten(IV) Iodide
- Tungsten Nitride WN
- Tungsten Nitride W3N2
- Tungsten(IV) Oxide WO2
- Tungsten(VI) Oxide WO3
- Tungsten Oxide Blue (Suboxide), WO2.9sub>
- Tungsten Oxide, Blue, W20sub>O58sub>
- Tungsten Oxide - Molybdenum Oxide
- Tungsten Oxide - Vanadium Oxide
- Tungsten(VI) Oxychloride
- Tungsten Disilicide WSi2
- Tungsten Silicide W5Si3
- Tungsten Silicide Sputtering Target
- Tungsten Tetrachloride
- Tungsten Titanium Carbide
- Tungsten Trioxide
- Tungstic Acid
- Tungstosilicic Acid Hydrate
- Zinc Tungstate
- Zirconiated Tungsten Electrode
- Zirconium Tungstate
Metallic Forms
- Black Tungsten Wire
- Gold-Plated Tungsten Gauze
- Potassium-doped Tungsten Wire
- Tungsten Balance Weights
- Tungsten Balls
- Tungsten Bands
- Tungsten Bar
- Tungsten Baskets
- Tungsten Blocks
- Tungsten Boats
- Tungsten Boring Bars
- Tungsten Chunk
- Tungsten Coil
- Tungsten Collimator Plates
- Tungsten Concentrate
- Tungsten Conductor Paste
- Tungsten Crucibles
- Tungsten Cubes
- Tungsten Cylinder
- Tungsten Disc
- Tungsten Electrodes
- Tungsten Filaments
- Tungsten Flanges
- Tungsten Foam
- Tungsten Foil
- Tungsten Furnace Elements
- Tungsten Granules
- Tungsten Grids
- Tungsten Gauze
- Tungsten Heat Shields
- Tungsten Honeycomb
- Tungsten Ingot
- Tungsten Insulated Wire
- Tungsten Lump
- Tungsten Mesh
- Tungsten Metal
- Tungsten Needles
- Tungsten Particles
- Tungsten Parts
- Tungsten Pellets
- Tungsten Pieces
- Tungsten Pins
- Tungsten Plate
- Tungsten Platens
- Tungsten Powder
- Tungsten Puck
- Tungsten Ribbon
- Tungsten Rings
- Tungsten Rod
- Tungsten Rods, Chrome-Plated
- Tungsten Samples
- Tungsten Shaving
- Tungsten Sheet
- Tungsten Shot
- Tungsten Sleeves
- Tungsten Slugs
- Tungsten Specimens
- Tungsten Spheres
- Tungsten Sponge
- Tungsten Spring
- Tungsten Squares
- Tungsten Strands
- Tungsten Strip
- Tungsten Syringe Shields
- Tungsten Tape
- Tungsten Wafer
- Tungsten Tube
- Tungsten Washer
- Tungsten Wire
- Tungsten Wire, Chromium-coated
- Tungsten Wire, Gold-coated
- Tungsten Wire, Platinum-coated
- Tungsten Wool
- Tungsten X-Ray Shields
Alloys
- Aluminum Copper Tungsten Alloy
- Aluminum Copper Tungsten Foil
- Barium Tungsten Alloy
- Cerium Tungsten Electrode
- Cobalt Chromium Nickel Tungsten Alloy
- Cobalt Chromium Tungsten Alloy
- Cobalt Chromium Tungsten Alloy Powder
- Cobalt Chromium Tungsten Nickel Iron Manganese Foil
- Cobalt Chromium Tungsten Nickel Manganese
- Cobalt Nickel Chromium Iron Molybdenum Tungsten Titanium
- Ferro Tungsten
- Gold-Coated Rhenium Tungsten Wire
- Inconel 686 Alloy
- Iron Aluminum Vanadium Alloy
- Lanthanated Tungsten Electrode
- Molybdenum Tungsten Alloy
- Platinum Tungsten Alloy
- Silver Tungsten Electrode
- Tantalum Tungsten Foil
- Thoriated Tungsten Electrode
- Tungsten Alloy Balance Weights
- Tungsten Alloy Collimator Plates
- Tungsten Carbide/Cobalt Rod
- Tungsten Carbide/Cobalt Sheet
- Tungsten Carbide/Cobalt Spheres
- Tungsten Carbide/Cobalt Tube
- Tungsten Carbide/Cobalt Wire
- Tungsten Carbide Copper Alloy
- Tungsten Copper Alloy
- Tungsten Copper Bar
- Tungsten Copper Foil
- Tungsten Copper Sheet
- Tungsten Copper Tube
- Tungsten Copper Wire
- Tungsten-Copper Electrodes
- Tungsten Manganese Alloy
- Tungsten Nickel Alloy
- Tungsten Nickel Foam
- Tungsten Nickel Honeycomb
- Tungsten Nickel Sponge
- Tungsten Nickel Wool
- Tungsten Nickel Copper Alloy
- Tungsten Nickel Copper Iron Alloy
- Tungsten Nickel Iron Alloy
- Tungsten Nickel Iron Molybdenum Alloy
- Tungsten Rhenium Alloy
- Tungsten Rhenium Foil
- Tungsten Rhenium Ribbon
- Tungsten Rhenium Rods
- Tungsten Rhenium Wire
- Tungsten Silicon Alloy
- Tungsten Silicon Foil
- Tungsten Silver Alloy
- Tungsten Titanium Alloy
- Tungsten Vanadium Alloy
- Tungsten Vanadium Foil
- Vanadium Tungsten Alloy
- Yttrium Tungsten Electrode
- Zirconium Tungsten Alloy
Oxide Forms
Organometallics
- (1,1'-Bis(diphenylphosphino) ferrocene)tetracarbonyltungsten(0)
- Barium Tungsten Isopropoxide
- Bis(acetonitrile)tetracarbonyltungsten(0)
- Bis(butylcyclopentadienyl)tungsten(IV) Dibromide
- Bis(cyclopentadienyl)tungsten(IV) Chloride Hydride
- Bis(cyclopentadienyl)tungsten(IV) Dichloride
- Bis(cyclopentadienyl)tungsten(IV) Dihydride
- Bis(ethylcyclopentadienyl)tungsten(IV) Dichloride
- Bis(ethylcyclopentadienyl)tungsten(IV) Dihydride
- Bis(isopropylcyclopentadienyl) tungsten(IV) Dichloride
- Bis(isopropylcyclopentadienyl) tungsten(IV) Dihydride
- Bis(tert-butylimino)bis(dimethylamino)tungsten(VI)
- Bis(tert-butylimino)bis(tert-butylamino)tungsten
- Cyclopentadienyltungsten(II) Tricarbonyl Chloride
- Cyclopentadienyltungsten(II) Tricarbonyl Hydride
- Dibromonitrosyl[tris(pyrazol-1-yl)borato]tungsten(II)
- Mesitylene Tungsten Tricarbonyl
- Methylamine Tungstate
- Oxotungsten Tetraisopropoxide
- Tetracarbonyl(1,5-cyclooctadiene)tungsten(0)
- Triamminetungsten(IV) Tricarbonyl
- Tris(3-hexyne)tungsten(0) Carbonyl
- Tris(acetonitrile)tricarbonyltungsten(0)
- Tris(tert-butoxy)(2,2-dimethylpropylidyne)tungsten(VI)
- Tungsten(0) Pentacarbonyl-N-pentylisonitrile
- Tungsten(V) Dichloride Triethoxide
- Tungsten(VI) Ethoxide
- Tungsten(VI) Ethoxide Solution
- Tungsten(V) Ethoxide
- Tungsten(V) Ethoxide 1,2-Dimethoxyethane Adduct
- Tungsten Hexacarbonyl
- Tungsten(VI) Isopropoxide
Nanomaterials
- Barium Tungstate Nanoparticles
- Cadmium Tungstate Nanoparticles
- Cesium Tungstate Nanoparticles
- Manganese Tungstate Nanowires
- Titanium Boride-Boron Carbide-Tungsten Boride Nanoparticles
- Tungsten Carbide Nanoparticles
- Tungsten Carbide - Cobalt Nanoparticles
- Tungsten Disulfide Nanoparticles
- Tungsten Disulfide Nanoparticle Dispersion
- Tungsten(VI) Oxide Nanoparticle Dispersion
- Tungsten Oxide Nanowires
- Tungsten Nanoparticles
- Tungsten Nanorods
- Tungsten Oxide Nanopowder
- Tungsten Sulfide Nanoparticles
Semiconductor & Optical
- Molybdenum Tungsten Diselenide
- Molybdenum Tungsten Disulfide
- Molybdenum Tungsten Ditelluride
- Neodymium doped Potassium Gadolinium Tungstate
- Potassium Gadolinium Tungstate (KGW)
- TaWSe2 Crystal
- Tungsten Diselenide
- Tungsten Diselenide Crystal
- Tungsten(IV) Diselenide, Lithium Intercalated
- Tungsten Disulfide
- Tungsten Disulfide Flakes
- Tungsten Disulfide Micropowder
- Tungsten Disulfide Ultrafine Powder
- Tungsten(IV) Disulfide, Iodine Intercalated
- Tungsten(IV) Disulfide, Lithium Intercalated
- Tungsten Ditelluride
- Tungsten Phosphide
- Tungsten Rhenium Diselenide
- Tungsten Selenide Flakes
- Tungsten Telluride
- WNbTe2 Crystal
- WTaSe4 Crystal
- Ytterbium doped Potassium Gadolinium Tungstate
- Ytterbium doped Potassium Yttrium Tungstate
Sputtering Targets
- Aluminum Copper Tungsten Sputtering Target
- Barium Tungsten Alloy Sputtering Target
- Calcium Tungstate Sputtering Target
- Cobalt Tungsten Sputtering Target
- Lithium Tungstate Sputtering Target
- Molybdenum Tungsten Sputtering Target
- Nickel Tungsten Sputtering Target
- Platinum Tungsten Alloy Sputtering Target
- Scandium Tungsten Alloy Sputtering Target
- Tin Oxide, Tungsten-doped Sputtering Target
- Tin Tungsten Alloy Sputtering Target
- Titanium Tungsten Sputtering Target
- Tungsten Boride WB Sputtering Target
- Tungsten Boride WB2 Sputtering Target
- Tungsten Boride W2B Sputtering Target
- Tungsten Carbide Sputtering Target
- Tungsten Carbide/Cobalt Sputtering Target
- Tungsten Copper Alloy Sputtering Target
- Tungsten Disilicide Sputtering Target
- Tungsten Disulfide Sputtering Target
- Tungsten Niobium Sputtering Target
- Tungsten Oxide Rotatable Sputtering Target
- Tungsten Oxide Sputtering Target
- Tungsten Phosphide Sputtering Target
- Tungsten Rhenium Alloy Sputtering Target
- Tungsten Rotatable Sputtering Target
- Tungsten Selenide Sputtering Target
- Tungsten Silicide Sputtering Target
- Tungsten Silicon Sputtering Target
- Tungsten Sputtering Target
- Tungsten Telluride Sputtering Target
- Tungsten Titanium Sputtering Target
- Tungsten Trioxide Sputtering Target
- Vanadium Tungsten Sputtering Target
- Zirconium Tungstate Sputtering Target
- Zirconium Tungsten Sputtering Target
Isotopes
Tungsten was first commercially used in incandescent and fluorescent light bulb filaments, and, later, in early television tubes. Tungsten expands at nearly the same rate as borosilicate glass and is used to make metal to glass seals. It is the primary metal in heating elements for electric furnaces and in many components where high pressure/ temperature environments are expected, such as aerospace and engine systems. Tungsten carbide is used in the production of industrial machinery, cutting tools, abrasives, and jewelry. Tungsten is available as metal and compounds with purities from 99% to 99.999% (ACS grade to ultra-high purity).
Elemental or metallic forms include pellets, rod, wire and granules for evaporation source material purposes. Tungsten nanoparticles and nanopowders provide ultra-high surface area. Tungsten oxides are available in powder and dense pellet form for such uses as optical coating and thin film applications. Oxides tend to be insoluble. Tungsten fluorides are another insoluble form for uses in which oxygen is undesirable such as metallurgy, chemical and physical vapor deposition and in some optical coatings. Tungsten is also available in soluble forms including chlorides. These compounds can be manufactured as solutions at specified stoichiometries.
American Elements assists our Tungsten customers with fulfilling the due diligence reporting requirements of the Conflict Mineral Provision (Section 1502) of the Dodd-Frank Act.
Tungsten Properties
Tungsten is a Block D, Group 6, Period 6 element. The number of electrons in each of tungsten's shells is 2, 8, 18, 32, 12, 2 and its electron configuration is [Xe] 4f14 5d4 6s2.
The tungsten atom has a radius of 137.pm and its Van der Waals radius is 200.pm. In its elemental form, CAS 7440-33-7, tungsten has a grayish white, lustrous appearance. Tungsten has the highest melting point of all the metallic elements.
It is found in the minerals scheelite (CaWO4) and wolframite [(Fe,Mn)WO4]. Tungsten was first discovered by Torbern Bergman in 1781 and first isolated by Juan José Elhuyar and Fausto Elhuyar in 1783. In reference to its density, Tungsten gets its name from the Swedish words tung and sten meaning heavy stone.
General Properties
Symbol: | W |
---|---|
Atomic Number: | 74 |
Atomic Weight: | 183.84 |
Element Category: | transition metal |
Group, Period, Block: | 6, 6, d |
Color: | grayish white, lustrous |
Other Names: | Wolframium, Tungsténe, Wolframio |
Physical Properties
Melting Point: | 3422 °C, 6192 °F, 3695 K |
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Boiling Point: | 5555 °C, 10031 °F, 5828 K |
Density: | 19.25 g·cm3 |
Liquid Density @ Melting Point: | 17.6 g·cm3 |
Density @ 20°C: | 19.3 g/cm3 |
Density of Solid: | 19250 kg·m3 |
Specific Heat: | 0.13 (kJ/kg K) |
Superconductivity Temperature: | 0.015 [or -273.135 °C (-459.64 °F)] K |
Triple Point: | 1941 K, 5.3 × 10 3 kPa |
Critical Point: | 13892 K, Mpa |
Heat of Fusion (kJ·mol-1): | 35.2 |
Heat of Vaporization (kJ·mol-1): | 824.2 |
Heat of Atomization (kJ·mol-1): | 848.1 |
Thermal Conductivity: | 173 W·m-1·K-1 |
Thermal Expansion: | (25 °C) 4.5 µm·m-1·K-1 |
Electrical Resistivity: | (20 °C) 52.8 nΩ·m |
Tensile Strength: | N/A |
Molar Heat Capacity: | 24.27 J·mol-1·K-1 |
Young's Modulus: | 411 GPa |
Shear Modulus: | 161 GPa |
Bulk Modulus: | 310 GPa |
Poisson Ratio: | 0.28 |
Mohs Hardness: | 7.8 |
Vickers Hardness: | 3430 MPa |
Brinell Hardness: | 2570 MPa |
Speed of Sound: | 4620 m·s-1 |
Pauling Electronegativity: | 2.36 |
Sanderson Electronegativity: | 0.98 |
Allred Rochow Electronegativity: | 1.4 |
Mulliken-Jaffe Electronegativity: | N/A |
Allen Electronegativity: | N/A |
Pauling Electropositivity: | 1.64 |
Reflectivity (%): | 62 |
Refractive Index: | N/A |
Chemical Properties
Electrons: | 74 |
---|---|
Protons: | 74 |
Neutrons: | 110 |
Electron Configuration: | [Xe] 4f14 5d4 6s2 |
Atomic Radius: | 139 pm |
Atomic Radius, non-bonded (Å): | 2.18 |
Covalent Radius: | 162±7 pm |
Covalent Radius (Å): | 1.5 |
Van der Waals Radius: | 200 pm |
Oxidation States: | 6, 5, 4, 3, 2, 1, 0, 1, -2 (mildly acidic oxide) |
Phase: | Solid |
Crystal Structure: | body-centered cubic |
Magnetic Ordering: | paramagnetic |
Electron Affinity (kJ·mol-1) | 78.732 |
1st Ionization Energy: | 770 kJ·mol-1 |
2nd Ionization Energy: | 770 kJ·mol-1 |
3rd Ionization Energy: | 1700 kJ·mol-1 |
Identifiers
CAS Number: | 7440-33-7 |
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EC Number: | 231-143-9 |
MDL Number: | MFCD00011461 |
Beilstein Number: | N/A |
SMILES Identifier: | [W] |
InChI Identifier: | InChI=1S/W |
InChI Key: | WFKWXMTUELFFGS-UHFFFAOYSA-N |
PubChem CID: | 23964 |
ChemSpider ID: | 22403 |
Abundance
Earth - Total: | 180 ppb |
---|---|
Mercury - Total: | 139 ppb |
Venus - Total: | 189 ppb |
Earth - Seawater (Oceans), ppb by weight: | 0.12 |
Earth - Seawater (Oceans), ppb by atoms: | 0.004 |
Earth - Crust (Crustal Rocks), ppb by weight: | 1100 |
Earth - Crust (Crustal Rocks), ppb by atoms: | 120 |
Sun - Total, ppb by weight: | 4 |
Sun - Total, ppb by atoms: | 0.03 |
Stream, ppb by weight: | 0.03 |
Stream, ppb by atoms: | 0.0002 |
Meterorite (Carbonaceous), ppb by weight: | 120 |
Meterorite (Carbonaceous), ppb by atoms: | 10 |
Typical Human Body, ppb by weight: | N/A |
Typical Human Body, ppb by atom: | N/A |
Universe, ppb by weight: | 0.5 |
Universe, ppb by atom: | 0.003 |
History
Discovered By: | Torbern Bergman |
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Discovery Date: | 1781 |
First Isolation: | Juan José Elhuyar and Fausto Elhuyar (1783) |
Health, Safety & Transportation Information for Tungsten
Tungsten is considered to be mildly toxic. Safety data for Tungsten and its compounds can vary widely depending on the form. For potential hazard information, toxicity, and road, sea and air transportation limitations, such as DOT Hazard Class, DOT Number, EU Number, NFPA Health rating and RTECS Class, please see the specific material or compound referenced in the Products tab. The below information applies to elemental (metallic) Tungsten.
Safety Data | |
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Signal Word | Danger |
Hazard Statements | H228-H315-H319 |
Hazard Codes | F,Xi |
Risk Codes | 11-36/38 |
Safety Precautions | 6-26/36 |
RTECS Number | YO7175000 |
Transport Information | N/A |
WGK Germany | 3 |
Globally Harmonized System of Classification and Labelling (GHS) | ![]() ![]() |
Review and Print SDS for Tungsten Metal
SAFETY DATA SHEET
SECTION 1. IDENTIFICATION
Product Name: Tungsten Metal
Product Number: All applicable American Elements product codes, e.g. W-M-02, W-M-03, W-M-04, W-M-05
CAS #: 7440-33-7
Relevant identified uses of the substance: Scientific research and development
Supplier details:
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SECTION 2. HAZARDS IDENTIFICATION
Classification of the substance or mixture
Classification according to Regulation (EC) No 1272/2008
The substance is not classified as hazardous to health or the environment according to the CLP regulation.
Classification according to Directive 67/548/EEC or Directive 1999/45/EC
Not applicable
Information concerning particular hazards for human and environment:
No information known.
Hazards not otherwise classified
No information known.
Label elements
Labelling according to Regulation (EC) No 1272/2008
Not applicable
Hazard pictograms
Not applicable
Signal word
Not applicable
Hazard statements
Not applicable
WHMIS classification
Not controlled
Classification system
HMIS ratings (scale 0-4)
(Hazardous Materials Identification System)
HEALTH
FIRE
REACTIVITY
0
0
0
Health (acute effects) = 0
Flammability = 0
Physical Hazard = 0
Other hazards
Results of PBT and vPvB assessment
PBT:
Not applicable.
vPvB:
Not applicable.
SECTION 3. COMPOSITION/INFORMATION ON INGREDIENTS
Chemical characterization: Substances
CAS# Description:
7440-33-7 Tungsten
Identification number(s):
EC number:
231-143-9
SECTION 4. FIRST AID MEASURES
Description of first aid measures
General information
No special measures required.
After inhalation
Seek medical treatment in case of complaints.
After skin contact
Generally the product does not irritate the skin.
After eye contact
Rinse opened eye for several minutes under running water. If symptoms persist, consult a doctor.
After swallowing
If symptoms persist consult doctor.
Information for doctor
Most important symptoms and effects, both acute and delayed
No further relevant information available.
Indication of any immediate medical attention and special treatment needed
No further relevant information available.
SECTION 5. FIREFIGHTING MEASURES
Extinguishing media
Suitable extinguishing agents
Special powder for metal fires. Do not use water.
For safety reasons unsuitable extinguishing agents
Water
Special hazards arising from the substance or mixture
If this product is involved in a fire, the following can be released:
Metal oxide fume
Advice for firefighters
Protective equipment:
No special measures required.
SECTION 6. ACCIDENTAL RELEASE MEASURES
Personal precautions, protective equipment and emergency procedures
Not required.
Environmental precautions:
Do not allow material to be released to the environment without proper governmental permits.
Do not allow product to reach sewage system or any water course.
Do not allow to penetrate the ground/soil.
Methods and material for containment and cleaning up:
Pick up mechanically
Prevention of secondary hazards:
No special measures required.
Reference to other sections
See Section 7 for information on safe handling
See Section 8 for information on personal protection equipment.
See Section 13 for disposal information.
SECTION 7. HANDLING AND STORAGE
Handling
Precautions for safe handling
Keep container tightly sealed.
Store in cool, dry place in tightly closed containers.
Information about protection against explosions and fires:
No special measures required.
Conditions for safe storage, including any incompatibilities
Storage
Requirements to be met by storerooms and receptacles:
No special requirements.
Information about storage in one common storage facility:
Do not store together with acids.
Further information about storage conditions:
Keep container tightly sealed.
Store in cool, dry conditions in well sealed containers.
Specific end use(s)
No further relevant information available.
SECTION 8. EXPOSURE CONTROLS/PERSONAL PROTECTION
Additional information about design of technical systems:
No further data; see section 7.
Control parameters
Components with limit values that require monitoring at the workplace:
7440-33-7 Tungsten (100.0%)
PEL (USA) and insoluble compounds, as We
REL (USA) Short-term value: 10 mg/m³
Long-term value: 5 mg/m³
as W
TLV (USA) Short-term value: 10 mg/m³
Long-term value: 5 mg/m³
as W
EL (Canada) Short-term value: 10 mg/m³
Long-term value: 5 mg/m³
as W
EV (Canada) Short-term value: 10* 3** mg/m³
Long-term value: 5* 1** mg/m³
(as tungsten; compds.:*water-insol.;**water-sol.
Additional information:
No data
Exposure controls
Personal protective equipment
General protective and hygienic measures
The usual precautionary measures for handling chemicals should be followed.
Maintain an ergonomically appropriate working environment.
Breathing equipment:
Not required.
Protection of hands:
Not required.
Penetration time of glove material (in minutes)
Not determined
Eye protection:
Safety glasses
Body protection:
Protective work clothing
SECTION 9. PHYSICAL AND CHEMICAL PROPERTIES
Information on basic physical and chemical properties
General Information
Appearance:
Form: Solid in various forms
Color: Silver grey
Odor: Not determined
Odor threshold: Not determined.
pH-value: Not applicable.
Change in condition
Melting point/Melting range: 3410 °C (6170 °F)
Boiling point/Boiling range: 5900 °C (10652 °F)
Sublimation temperature / start: Not determined
Flammability (solid, gaseous)
Not determined.
Ignition temperature: Not determined
Decomposition temperature: Not determined
Auto igniting: Not determined.
Danger of explosion: Not determined.
Explosion limits:
Lower: Not determined
Upper: Not determined
Vapor pressure: Not applicable.
Density at 20 °C (68 °F): 19.3 g/cm³ (161.059 lbs/gal)
Bulk density at 20 °C (68 °F): 4000 kg/m³
Relative density
Not determined.
Vapor density
Not applicable.
Evaporation rate
Not applicable.
Solubility in / Miscibility with Water: Insoluble
Partition coefficient (n-octanol/water): Not determined.
Viscosity:
dynamic: Not applicable.
kinematic: Not applicable
Other information
No further relevant information available
SECTION 10. STABILITY AND REACTIVITY
Reactivity
No information known.
Chemical stability
Stable under recommended storage conditions.
Thermal decomposition / conditions to be avoided:
Decomposition will not occur if used and stored according to specifications.
Possibility of hazardous reactions
No dangerous reactions known
Conditions to avoid
No further relevant information available.
Incompatible materials:
Acids
Hazardous decomposition products:
Metal oxide fume
SECTION 11. TOXICOLOGICAL INFORMATION
Information on toxicological effects
Acute toxicity:
The Registry of Toxic Effects of Chemical Substances (RTECS) contains acute toxicity data for components in this product.
LD/LC50 values that are relevant for classification:
No data
Skin irritation or corrosion:
No irritant effect.
Eye irritation or corrosion:
No irritant effect.
Sensitization:
No sensitizing effects known.
Germ cell mutagenicity:
No effects known.
Carcinogenicity:
No classification data on carcinogenic properties of this material is available from the EPA, IARC, NTP, OSHA or ACGIH.
Reproductive toxicity:
The Registry of Toxic Effects of Chemical Substances (RTECS) contains reproductive data for this substance.
Specific target organ system toxicity - repeated exposure:
No effects known.
Specific target organ system toxicity - single exposure:
No effects known.
Aspiration hazard:
No effects known.
Subacute to chronic toxicity:
No effects known.
Additional toxicological information:
To the best of our knowledge the acute and chronic toxicity of this substance is not fully known.
SECTION 12. ECOLOGICAL INFORMATION
Toxicity
Aquatic toxicity:
No further relevant information available.
Persistence and degradability
No further relevant information available.
Bioaccumulative potential
No further relevant information available.
Mobility in soil
No further relevant information available.
Additional ecological information:
General notes:
Do not allow material to be released to the environment without proper governmental permits.
Do not allow undiluted product or large quantities to reach ground water, water course or sewage system.
Avoid transfer into the environment.
Results of PBT and vPvB assessment
PBT:
Not applicable.
vPvB:
Not applicable.
Other adverse effects
No further relevant information available.
SECTION 13. DISPOSAL CONSIDERATIONS
Waste treatment methods
Recommendation
Consult state, local or national regulations to ensure proper disposal.
Uncleaned packagings:
Recommendation:
Disposal must be made according to official regulations.
SECTION 14. TRANSPORT INFORMATION
UN-Number
DOT, ADN, IMDG, IATA
Not applicable
UN proper shipping name
DOT, ADN, IMDG, IATA
Not applicable
Transport hazard class(es)
DOT, ADR, ADN, IMDG, IATA
Class
Not applicable
Packing group
DOT, IMDG, IATA
Not applicable
Environmental hazards:
Not applicable.
Special precautions for user
Not applicable.
Transport in bulk according to Annex II of MARPOL73/78 and the IBC Code
Not applicable.
Transport/Additional information:
DOT
Marine Pollutant (DOT):
No
SECTION 15. REGULATORY INFORMATION
Safety, health and environmental regulations/legislation specific for the substance or mixture
National regulations
All components of this product are listed in the U.S. Environmental Protection Agency Toxic Substances Control Act Chemical substance Inventory.
All components of this product are listed on the Canadian Domestic Substances List (DSL).
SARA Section 313 (specific toxic chemical listings)
Substance is not listed.
California Proposition 65
Prop 65 - Chemicals known to cause cancer
Substance is not listed.
Prop 65 - Developmental toxicity
Substance is not listed.
Prop 65 - Developmental toxicity, female
Substance is not listed.
Prop 65 - Developmental toxicity, male
Substance is not listed.
Information about limitation of use:
For use only by technically qualified individuals.
Other regulations, limitations and prohibitive regulations
Substance of Very High Concern (SVHC) according to the REACH Regulations (EC) No. 1907/2006.
Substance is not listed.
The conditions of restrictions according to Article 67 and Annex XVII of the Regulation (EC) No 1907/2006 (REACH) for the manufacturing, placing on the market and use must be observed.
Substance is not listed.
Annex XIV of the REACH Regulations (requiring Authorisation for use)
Substance is not listed.
REACH - Pre-registered substances
Substance is listed.
Chemical safety assessment:
A Chemical Safety Assessment has not been carried out.
16. OTHER INFORMATION
Safety Data Sheet according to Regulation (EC) No. 1907/2006 (REACH). The above information is believed to be correct but does not purport to be all inclusive and shall be used only as a guide. The information in this document is based on the present state of our knowledge and is applicable to the product with regard to appropriate safety precautions. It does not represent any guarantee of the properties of the product. American Elements shall not be held liable for any damage resulting from handling or from contact with the above product. See reverse side of invoice or packing slip for additional terms and conditions of sale. COPYRIGHT 1997-2016 AMERICAN ELEMENTS. LICENSED GRANTED TO MAKE UNLIMITED PAPER COPIES FOR INTERNAL USE ONLY.
Tungsten Isotopes
Naturally occurring tungsten (W) has four stable isotopes: 182W, 183W, 184W, and 186W. Additionally, 180W has an long half-life of 1.8 ± 0.2 Ea (1018 years).
Nuclide | Isotopic Mass | Half-Life | Mode of Decay | Nuclear Spin | Magnetic Moment | Binding Energy (MeV) | Natural Abundance (% by atom) |
---|---|---|---|---|---|---|---|
158W | 157.97456(54)# | 1.37(17) ms | a to 154Hf | 0+ | N/A | 1221.35 | - |
159W | 158.97292(43)# | 8.2(7) ms | a to 155Hf; ß+ to 159Ta | 7/2-# | N/A | 1229.43 | - |
160W | 159.96848(22) | 90(5) ms | a to 156Hf; ß+ to 160Ta | 0+ | N/A | 1246.83 | - |
161W | 160.96736(21)# | 409(16) ms | a to 157Hf; ß+ to 161Ta | 7/2-# | N/A | 1254.9 | - |
162W | 161.963497(19) | 1.36(7) s | ß+ to 162Ta; a to 158Hf | 0+ | N/A | 1262.98 | - |
163W | 162.96252(6) | 2.8(2) s | ß+ to 163Ta; a to 159Hf | 3/2-# | N/A | 1271.06 | - |
164W | 163.958954(13) | 6.3(2) s | ß+ to 164Ta; a to 160Hf | 0+ | N/A | 1288.46 | - |
165W | 164.958280(27) | 5.1(5) s | ß+ to 165Ta; a to 161Hf | 3/2-# | N/A | 1296.54 | - |
166W | 165.955027(11) | 19.2(6) s | ß+ to 166Ta; a to 162Hf | 0+ | N/A | 1304.61 | - |
167W | 166.954816(21) | 19.9(5) s | ß+ to 167Ta; a to 163Hf | 3/2-# | N/A | 1312.69 | - |
168W | 167.951808(17) | 51(2) s | ß+ to 168Ta; a to 164Hf | 0+ | N/A | 1320.77 | - |
169W | 168.951779(17) | 76(6) s | ß+ to 169Ta | (5/2-) | N/A | 1328.85 | - |
170W | 169.949228(16) | 2.42(4) min | ß+ to 170Ta; a to 166Hf | 0+ | N/A | 1346.25 | - |
171W | 170.94945(3) | 2.38(4) min | ß+ to 171Ta | (5/2-) | N/A | 1354.32 | - |
172W | 171.94729(3) | 6.6(9) min | ß+ to 172Ta | 0+ | N/A | 1362.4 | - |
173W | 172.94769(3) | 7.6(2) min | ß+ to 173Ta | 5/2- | N/A | 1370.48 | - |
174W | 173.94608(3) | 33.2(21) min | ß+ to 174Ta | 0+ | N/A | 1378.56 | - |
175W | 174.94672(3) | 35.2(6) min | ß+ to 175Ta | (1/2-) | N/A | 1386.64 | - |
176W | 175.94563(3) | 2.5(1) h | EC to 176Ta | 0+ | N/A | 1394.72 | - |
177W | 176.94664(3) | 132(2) min | ß+ to 177Ta | 1/2- | N/A | 1402.8 | - |
178W | 177.945876(16) | 21.6(3) d | EC to 178Ta | 0+ | N/A | 1410.88 | - |
179W | 178.947070(17) | 37.05(16) min | EC to 179Ta | (7/2)- | N/A | 1418.95 | - |
180W | 179.946704(4) | 1.8(0.2)x1018 y | a to 176Hf | 0+ | N/A | 1427.03 | 0.12 |
181W | 180.948197(5) | 121.2(2) d | EC to 181Ta | 9/2+ | N/A | 1435.11 | - |
182W | 181.9482042(9) | Observationally Stable | - | 0+ | N/A | 1443.19 | 26.5 |
183W | 182.9502230(9) | Observationally Stable | - | 1/2- | 0.1177847 | 1441.95 | 14.31 |
184W | 183.9509312(9) | Observationally Stable | - | 0+ | N/A | 1450.03 | 30.64 |
185W | 184.9534193(10) | 75.1(3) d | ß- to 185Re | 3/2- | N/A | 1458.11 | - |
186W | 185.9543641(19) | Observationally Stable | - | 0+ | N/A | 1466.19 | 28.43 |
187W | 186.9571605(19) | 23.72(6) h | ß- to 187Re | 3/2- | 0.62 | 1474.27 | - |
188W | 187.958489(4) | 69.78(5) d | ß- to 188Re | 0+ | N/A | 1482.35 | - |
189W | 188.96191(21) | 11.6(3) min | ß- to 189Re | (3/2-) | N/A | 1481.11 | - |
190W | 189.96318(18) | 30.0(15) min | Unknown | 0+ | N/A | 1489.19 | - |
191W | 190.96660(21)# | 20# s [>300 ns] | Unknown | 3/2-# | N/A | 1497.27 | - |
192W | 191.96817(64)# | 10# s [>300 ns] | Unknown | 0+ | N/A | 1505.34 | - |