Chromium
About Chromium

When French chemist Louis Nicolas Vauquelin first received a sample of Siberian red lead in 1797, the mineral--known today as crocoite--had been in use as a pigment for over three decades, but its chemical composition had remained a subject of dispute. Vauquelin resolved the debate when he was able to isolate a new metallic element, chromium, from the sample, a discovery he reported in the scientific literature the following year. The process he used to isolate pure chromium metal had produced a variety of vibrantly colored solutions and compounds, and it was due to this that Vauquelin’s colleagues had suggested the element be named from chroma, Greek for “color”. Vauquelin went on to detect traces of chromium in precious gems such as rubies and emeralds, and to hypothesize correctly that chromium gave these gems their brilliant colors.
The earliest uses of chromium exploited its compounds. Lead chromate, the main compound in crocoite, was used to produce a pigment called “chrome yellow”, a color well known due to its widespread use for school buses in the United States and postal vehicles in some European countries. Use of actual lead chromate has declined significantly due to toxicity concerns, but the color is still used, replicated using less toxic alternatives. Viridian, a green pigment produced from chromium(III) oxide, is not toxic and is still used widely in ceramics and glassware. Other chromium(III) compounds have been used in tanning since the early 19th century, as a reaction between chromium and the collagen fibers stabilizes leather.
Chromium compounds continue to find applications in industry. A number of chemical processes use chromium-containing catalysts including the production of polyethylene, the most common form of plastic. Chromium salts are used in wood preservatives, and chromium provides color to synthetic rubies and emeralds. The first laser was built using a synthetic ruby. Both chromite and chromium(III) oxide can withstand high temperatures, and are frequently used as refractory materials such as brick molds and foundry sands. Chromium (IV) oxide is magnetic, and is used to manufacture the magnetic tape used in audio cassettes.
The vast majority of chromium is used in metalworking , either as a component of alloys or in various types of surface treatments. Chromium strengthens and imparts corrosion resistance to alloys. High-speed tool steels include small percentages of chromium for added strength, while higher percentages of chromium produce stainless steel. Additionally, nickel-based superalloys derive increased strength from the inclusion of chromium; these alloys are frequently found in devices such as jet engines that require materials to be stable and strong at very high temperatures. Chromium can be applied to metal surfaces via electroplating, and such surface treatments can provide wear resistance and, because chromium can be polished to an appealing silvery sheen, decoration. Additionally, chromic acid is used in chromate conversion coating, which produces a distinctive yellow finish on metal surfaces that may be used for corrosion inhibition or as a primer for further coatings. Anodization of aluminum is yet another finishing process that utilizes chromic acid, though it does not produce a chromium-containing coating.
Unfortunately, chromium(VI), known commonly as hexavalent chromium, is now known to be a potent carcinogen. Hexavalent chromium ions wreak havoc in the body because they are strong oxidizing agents that are easily transported into cells, where they cause significant damage to DNA and proteins. Many industrial processes that involve chromium, including chrome plating and chromium conversion coating, usually use hexavalent forms of chromium, and therefore the contamination of groundwater with hexavalent chromium from industrial waste is a major environmental problem. Alternative processes using trivalent chromium, which does not present the same toxicity concerns, are under investigation, as use and disposal of hexavalent chromium is now highly regulated.
Chromium is mined as chromite, an iron chromium oxide mineral. This ore can be processed either to pure chromium metal or to ferrochrome, an iron-chrome alloy used primarily in the production of stainless steel. Chromium can also be recovered from scrap, and recycled metal accounts for almost a third of chromium used annually.
Products
Compounds
- Ammonium Chromate
- Ammonium Chromium(III) Sulfate Dodecahydrate
- Ammonium Dichromate
- Barium(V) Chromate Ba3Cr2O8
- Barium(VI) Chromate BaCrO4
- Barium Dichromate Dihydrate
- Bismuth Chromate
- Bismuth(III) Dichromate
- Bismuth Oxychromate
- Cadmium Chromate
- Calcium Chromate
- Calcium Dichromate
- Calcium Lanthanum Chromite
- Cerium Chromate
- Cesium Chromate
- Cesium Dichromate
- Chromium Acetate
- Chromium Acetate Solution
- Chromium(III) Acetate Hydroxide
- Chromium Aluminum Carbide
- Chromium Boride CrB
- Chromium Diboride CrB2
- Chromium Boride Cr2B
- Chromium Boride Cr5B3
- Chromium Bromide CrBr2
- Chromium Bromide CrBr3
- Chromium(III) Bromide Hexahydrate
- Chromium Carbide Cr2C
- Chromium Carbide Cr3C2
- Chromium Carbide Cr7C3
- Chromium Carbide Cr23C6
- Chromium Carbide Powder
- Chromium Carbonate
- Chromium(II) Chloride
- Chromium Chloride Solution
- Chromium(III) Chloride
- Chromium(III) Chloride Hexahydrate
- Chromium(III) Chloride Hydrate
- Chromium Chloride, Basic
- Chromium Difluoride
- Chromium Fluoride
- Chromium Fluoride, Ultra Dry
- Chromium(III) Fluoride Tetrahydrate
- Chromium Hydroxide
- Chromium Hydroxy Nitrate
- Chromium(II) Iodide
- Chromium(III) Iodide
- Chromium Nitrate
- Chromium Nitrate Solution
- Chromium Nitride CrN
- Chromium Nitride Cr2N
- Chromium Oxalate
- Chromium(III) Oxide
- Chromium(III) Oxide Hydrate
- Chromium(IV) Oxide
- Chromium Perchlorate Hexahydrate
- Chromium Phosphate
- Chromium Phosphate Hydrate
- Chromium Phosphate Tetrahydrate
- Chromium Potassium Sulfate
- Chromium Potassium Sulfate Dodecahydrate
- Chromium Potassium Sulfate Solution
- Chromium Silicon Oxide
- Chromium Stearate
- Chromium Sulfate
- Chromium Sulfate Basic
- Chromium Sulfate Hydrate
- Chromium Sulfate Solution
- Chromium Trioxide
- Chromium tris(dihydrogen phosphate)
- Chromyl Chloride
- Cobalt(II) Chromate
- Cobalt Chromate
- Copper Chromate
- Copper Chromite
- Copper Chromite, Barium Promoted
- Doped Lanthanum Chromite Paste
- Iron Chromate
- Iron Chromite
- Lanthanum Chromite
- Lanthanum Strontium Chromite
- Lanthanum Strontium Cobalt Chromite
- Lanthanum Strontium Cobalt Chromite Paste
- Lead Chromate
- Lead Chromate Oxide
- Lithium Chromate
- Lithium Chromate Hydrate
- Magnesium Chromate
- Magnesium Chromate Hydrate
- Magnesium Dichromate
- Manganese Chromate
- Mercury(I) Chromate
- Mercury(II) Chromate
- Nickel Chromate
- Nickel Chromite
- Niobium Chromide
- Pentazinc Chromate Octahydroxide
- Pigment Yellow 34
- Potassium Chlorochromate
- Potassium Chromate
- Potassium Chromate Solution
- Potassium Chromium(III) Oxalate Trihydrate
- Potassium Hexacyanochromate(III)
- Potassium Trioxalatochromate
- Reinecke Salt
- Rubidium Chromate
- Rubidium Dichromate
- Silver Dichromate
- Sodium Chromate
- Sodium Chromate Tetrahydrate
- Sodium Dichromate
- Sodium Dichromate Dihydrate
- Strontium Dichromate
- Thallium Dichromate
- Tin Chromate
- Zinc Chromate
- Zinc Dichromate Trihydrate
Metallic Forms
- Chromium Balls
- Chromium Bands
- Chromium Bars
- Chromium Blocks
- Chromium Chips
- Chromium Chunk
- Chromium Coil
- Chromium Concentrate
- Chromium Crucibles
- Chromium Crystallite Pieces
- Chromium Cubes
- Chromium Cylinder
- Chromium Disc
- Chromium Flake
- Chromium Flanges
- Chromium Foil
- Chromium Granules
- Chromium Grit
- Chromium Ingot
- Chromium Lump
- Chromium Mesh
- Chromium Metal
- Chromium Microfoil
- Chromium Microleaf
- Chromium Particles
- Chromium Parts
- Chromium Pellets
- Chromium Pieces
- Chromium Plate
- Chromium Powder
- Chromium Puck
- Chromium Ribbon
- Chromium Rings
- Chromium Rod
- Chromium Samples
- Chromium Shaving
- Chromium Sheets
- Chromium Shot
- Chromium Single Crystal
- Chromium Sleeves
- Chromium Slug
- Chromium Specimens
- Chromium Spheres
- Chromium Spring
- Chromium Strip
- Chromium Tape
- Chromium Tube
- Chromium Wafer
- Chromium Wire
- Ultra Thin Chromium Foil
Alloys
- Aluminum Chromium Alloy
- Aluminum Manganese Chromium Alloy
- Aluminum Molybdenum Vanadium Chromium Titanium Alloy
- Aluminum Zinc Magnesium Copper Chromium Alloy
- Carbon Steel Cut Wire Shot
- Carpenter 20 Alloy
- Chrome-Plated Tungsten Rods
- Chromium Aluminium Yttrium Alloy
- Chromium Aluminium Yttrium Alloy Particles
- Chromium Carbide - Nickel Chromium Composite Powder
- Chromium Cobalt Alloy
- Chromium Cobalt Iron
- Chromium Cobalt Nickel
- Chromium Cobalt Platinum Alloy
- Chromium Cobalt Platinum Tantalum
- Chromium Cobalt Sputtering Target
- Chromium Cobalt Tantalum
- Chromium Copper Alloy
- Chromium Iron Carbon Silicon Alloy Particles
- Chromium Iron Carbon Silicon Alloy Powder
- Chromium Iron Nickel
- Chromium Iron Tantalum Alloy
- Chromium Iron Titanium Alloy
- Chromium Iron Yttrium Alloy
- Chromium Magnesium Alloy
- Chromium Manganese Palladium
- Chromium Manganese Platinum Alloy
- Chromium Molybdenum Alloy
- Chromium Nickel Alloy
- Chromium Nickel Copper Alloy
- Chromium Nickel Silicon Alloy
- Chromium Nickel Tungsten Alloy
- Chromium Ruthenium
- Chromium Silicon Alloy
- Chromium Tin Alloy
- Chromium Titanium Alloy
- Chromium Vanadium Alloy
- Chromium Yttrium Alloy
- Cobalt Chromium Alloy
- Cobalt Chromium Aluminum Alloy
- Cobalt Chromium Aluminum Vanadium Alloy
- Cobalt Chromium Foam
- Cobalt Chromium Honeycomb
- Cobalt Chromium Metals Alloy Particles
- Cobalt Chromium Molybdenum Alloy
- Cobalt Chromium Molybdenum Powder
- Cobalt Chromium Nickel Iron Molybdenum Manganese
- Cobalt Chromium Nickel Tungsten Alloy
- Cobalt Chromium Powder
- Cobalt Chromium Sponge
- Cobalt Chromium Transition Metals Alloy Powder
- Cobalt Chromium Tungsten Alloy
- Cobalt Chromium Tungsten Alloy Powder
- Cobalt Chromium Tungsten Nickel Iron Manganese Foil
- Cobalt Chromium Tungsten Nickel Manganese
- Cobalt Chromium Wool
- Cobalt Nickel Chromium Alloy
- Cobalt Nickel Chromium Iron Molybdenum Titanium
- Cobalt Nickel Chromium Iron Molybdenum Tungsten Titanium
- Cobalt Nickel Chromium Molybdenum Alloy
- Copper Chromium Alloy
- Copper Chromium Nickel Silicon Alloy
- Copper Chromium Zirconium Alloy
- Copper Chromium Zirconium Alloy Particles
- Copper Chromium Zirconium Alloy Powder
- Electroloy Alloy
- Ferro Chromium
- H13 Steel Powder
- Hastelloy B Alloy
- Hastelloy C-22 Alloy
- Hastelloy C-276 Alloy
- Hastelloy C276 Foil
- Hastelloy X Alloy
- Havar Alloy Foil
- High-Entropy Alloy 3D Printing Powder
- Inconel 600 Alloy
- Inconel 600 Alloy Foil
- Inconel 600 Alloy Powder
- Inconel 601 Alloy
- Inconel 617 Alloy
- Inconel 625 Alloy
- Inconel 625 Powder
- Inconel 686 Alloy
- Inconel 690 Alloy
- Inconel 693 Alloy
- Inconel 713C Powder
- Inconel 718 Alloy
- Inconel 718 Powder
- Inconel 738 Alloy
- Inconel 825 Alloy
- Inconel 925 Alloy
- Inconel Crucible
- Inconel X-750 Alloy
- Inconel X-750 Powder
- Iron Chromium
- Iron Chromium Aluminum Alloy
- Iron Chromium Aluminum Foam
- Iron Chromium Aluminum Honeycomb
- Iron Chromium Aluminum Powder
- Iron Chromium Aluminum Sponge
- Iron Chromium Aluminum Wool
- Iron Chromium Aluminum Yttrium Alloy
- Iron Chromium Aluminum Yttrium Powder
- Iron Chromium Carbon Alloy Particles
- Iron Chromium Carbon Alloy Powder
- Iron Chromium Foam
- Iron Chromium Honeycomb
- Iron Chromium Molybdenum Alloy
- Iron Chromium Molybdenum Foil
- Iron Chromium Nickel Alloy
- Iron Chromium Nickel Aluminum
- Iron Chromium Nickel Copper Alloy
- Iron Chromium Nickel Copper Molybdenum Niobium
- Iron Chromium Nickel Copper Niobium
- Iron Chromium Nickel Copper Titanium Niobium
- Iron Chromium Nickel Manganese Molybdenum
- Iron Chromium Nickel Molybdenum
- Iron Chromium Nickel Molybdenum Aluminum
- Iron Chromium Nickel Titanium Molybdenum
- Iron Chromium Powder
- Iron Chromium Sponge
- Iron Chromium Wool
- Iron Manangese Chromium Molybdenum Nitrogen
- Iron Nickel Chromium Alloy
- Molybdenum Chromium Alloy
- Nickel Chromium Alloy
- Nickel Chromium Aluminum Alloy
- Nickel Chromium Aluminum Cobalt Alloy
- Nickel Chromium Aluminum Foam
- Nickel Chromium Aluminum Honeycomb
- Nickel Chromium Aluminum Sponge
- Nickel Chromium Aluminum Wool
- Nickel Chromium Aluminum Yttrium Alloy
- Nickel Chromium Aluminum Yttrium Powder
- Nickel Chromium Boron Alloy
- Nickel Chromium Canes
- Nickel Chromium Cobalt Alloy
- Nickel Chromium Cobalt Molybdenum Titanium Aluminum Alloy
- Nickel Chromium Cobalt Molybdenum Titanium Aluminum Iron Alloy
- Nickel Chromium Cobalt Powder
- Nickel Chromium Foam
- Nickel Chromium Foil
- Nickel Chromium Gauze
- Nickel Chromium Honeycomb
- Nickel Chromium Iron Alloy
- Nickel Chromium Iron Molybdenum Alloy
- Nickel Chromium Iron Silicon Boron Alloy
- Nickel Chromium Iron Silicon Boron Alloy Particles
- Nickel Chromium Microfoil
- Nickel Chromium Molybdenum Boron Alloy
- Nickel Chromium Molybdenum Boron Alloy Particles
- Nickel Chromium Molybdenum Iron Alloy
- Nickel Chromium Pellets
- Nickel Chromium Powder
- Nickel Chromium Slugs
- Nickel Chromium Sponge
- Nickel Chromium Tungsten Alloy
- Nickel Chromium Wool
- Nickel Cobalt Chromium Alloy
- Nickel Cobalt Chromium Aluminum Yttrium Powder
- Nickel Iron Chromium Alloy
- Nickel Iron Chromium Foam
- Nickel Iron Chromium Honeycomb
- Nickel Iron Chromium Molybdenum Alloy
- Nickel Iron Chromium Molybdenum Titanium Alloy
- Nickel Iron Chromium Sponge
- Nickel Iron Chromium Wool
- Nickel Molybdenum Chromium Iron Alloy
- Nickel Molybdenum Iron Chromium Alloy
- Niobium Titanium Chromium Aluminum Alloy
- Palladium Chromium Foil
- Protoloy Alloy
- Stainless Steel Electrodes
- Stainless Steel Foam
- Stainless Steel Foil
- Stainless Steel Insulated Wire
- Stainless Steel Mesh
- Stainless Steel Powder
- Stainless Steel Shot
- Stainless Steel Tube
- Stainless Steel Wire
- Titanium Aluminum Chromium Alloy
- Titanium Aluminum Chromium Foil
- Titanium Chromium Alloy
- Titanium Vanadium Chromium Aluminium Foil
- Titanium Vanadium Chromium Manganese Alloy
- Tungsten Chromium Alloy
- Vanadium Chromium Alloy
Oxide Forms
- Chromium-doped Silicon Monoxide Sputtering Target
- Chromium Oxide Nanoparticles
- Chromium Oxide Particles
- Chromium Oxide Pellets
- Chromium Oxide Pieces
- Chromium Oxide Powder
- Chromium Oxide Rotatable Sputtering Target
- Chromium Oxide Shot
- Chromium Oxide Sputtering Target
- Chromium Silicon Oxide
- Chromium Oxide Tablets
- Chromium Oxide/Silicon Oxide Pieces
- Chromium Trioxide Flakes
- Chromium Trioxide Sputtering Targets
- Jones Reagent
Organometallics
- [1,1'-Bis(diphenylphosphino)ferrocene] tetracarbonylchromium(0)
- (1S,2S)-(+)-[1,2-Cyclohexanediamino-N,N'-bis(3,5-di-t-butylsalicylidene)]chromium(III) Chloride
- Benzene-chromium(0) Tricarbonyl
- Bis(benzene)chromium(0)
- Bis(cyclopentadienyl)chromium(II)
- Bis(ethylbenzene)chromium
- Bis(ethylcyclopentadienyl)chromium(II)
- Bis(i-propylcyclopentadienyl)chromium
- Bis(pentamethylcyclopentadienyl)chromium(II)
- Bis(tetramethylcyclopentadienyl)chromium(II)
- Bis(triphenylsilyl) Chromate
- Chromium 2-Ethylhexanoate
- Chromium(II) Acetate, Dimer Monohydrate
- Chromium Acetylacetonate
- Chromium(III) Benzoylacetonate
- Chromium(III) Chloride Tetrahydrofuran Complex
- Chromium Citrate
- Chromium(0) Hexacarbonyl
- Chromium(III) Hexafluoroacetylacetonate
- Chromium(III) Naphthenate
- Chromium Nicotinate
- Chromium(III) Picolinate
- Chromium(III) Tetraphenylporphine Chloride
- Chromium(III) Trifluoroacetylacetonate
- Chromium Trifluoromethanesulfonate
- Chromium Tris(2,2,6,6-tetramethyl-3,5 -heptanedionate)
- Dicarbonyl(pentamethylcyclopentadienyl) Chromium(V) Dimer
- (Ethyl benzoate)tricarbonylchromium
- Fluorochromium Phthalocyanine
- (Methyl benzoate)tricarbonylchromium
- [N,N'-Bis(3,5-di-tert-butylsalicylidene) -1,2-phenylenediaminochromium-di-THF]tetracarbonylcobaltate
- Pyridinium Chlorochromate
- (R,R)-N,N′-Bis(3,5-di-tert-butylsalicylidene)-1,2-cyclohexanediaminochromium(III) Chloride
- Tetramethylammonium (1-hydroxyethylidene)pentacarbonylchromium
- Tricarbonyl(mesitylene)chromium(0)
- Tris(acetonitrile)tricarbonylchromium(0)
- Tris(ethylenediamine)chromium(III) Chloride Hemiheptahydrate
- (Toluene)tricarbonylchromium
Nanomaterials
- Chromium Carbide Nanoparticles
- Chromium Cobalt Iron Nanoparticles
- Chromium Nanoparticles
- Chromium Nanoparticle Dispersion
- Chromium Nanoprisms
- Chromium Nanorods
- Chromium Oxide Nanoparticles
- Chromium Nitrate Nanopowder
- Nickel Chromium Oxide Nanoparticle Dispersion
- Nickel Chromium Oxide Nanoparticles
- Nickel Chromium Nanoparticles
- Nickel Chromium Aluminum Yttrium Nanoparticles
- Nickel Cobalt Chromium Aluminum Yttrium Nanoparticles
- Nickel Cobalt Chromium Nanoparticles
Semiconductor & Optical
- AgCrSe2 Crystal
- Alexandrite Rods
- Chromium Antimonide
- Chromium Arsenide
- Chromium Doped Silicon Oxide
- Chromium, Erbium: Yttrium Scandium Gallium Garnet
- Chromium Phosphide
- Chromium Selenide
- Chromium(II) Silicide Cr3Si2
- Chromium Silicide CrSi2
- Chromium Silicide Cr3Si
- Chromium Sulfide
- Chromium Telluride
- CTH:YAG (Cr,Tm,Ho:YAG)
- CrBi2Te4 Crystal
- CrBi4Te7 Crystal
- CrGeTe3 Crystal
- Cr2Ge2Te6 Crystal
- CrPS4 Crystal
- Cr2Si2Te6 Crystal
- CrSiTe3 Crystal
- CrTe2 Crystal
- CuCrP2S6 Crystal
- Ruby Powder
- Ruby Sheet
- Ruby Spheres
- Yttrium Aluminum Garnet (YAG) doped with Chromium
Sputtering Targets
- Aluminum 5052 Sputtering Target
- Aluminum Chromium Sputtering Target
- Aluminum Copper Magnesium Chromium Zinc Sputtering Target
- Aluminum Copper Magnesium Chromium Zinc Rotatable Sputtering Target
- Aluminum Manganese Chromium Rotatable Sputtering Target
- Aluminum Manganese Chromium Sputtering Target
- Aluminum Oxide-Chromium Oxide Sputtering Target
- Aluminum Silicon Copper Magnesium Chromium Rotatable Sputtering Target
- Aluminum Silicon Copper Magnesium Chromium Sputtering Target
- Chromium Aluminum Sputtering Target
- Chromium Aluminum Yttrium Alloy Sputtering Target
- Chromium Antimonide Sputtering Target
- Chromium Boride CrB Sputtering Target
- Chromium-Boride Silicon Carbide Sputtering Target
- Chromium Boron Sputtering Target
- Chromium Carbide Sputtering Targets
- Chromium Cobalt Sputtering Target
- Chromium Cobalt Platinum Alloy Sputtering Target
- Chromium Copper Sputtering Target
- Chromium Diboride Sputtering Target
- Chromium Disilicide Sputtering Target
- Chromium-doped Silicon Monoxide Sputtering Target
- Chromium Fluoride Sputtering Target
- Chromium Manganese Sputtering Target
- Chromium Molybdenum Sputtering Target
- Chromium Molybdenum Tantalum Sputtering Target
- Chromium Nickel Sputtering Target
- Chromium Nickel Silicon Sputtering Target
- Chromium Nitride (Cr2sub>N) Sputtering Target
- Chromium(III) Nitride (CrN) Sputtering Target
- Chromium Oxide Rotatable Sputtering Target
- Chromium Oxide Sputtering Target
- Chromium Rotatable Sputtering Target
- Chromium Selenide Sputtering Target
- Chromium Silicide Sputtering Target
- Chromium Silicon Oxide Sputtering Target
- Chromium Silicon Sputtering Target
- Chromium Sputtering Target
- Chromium Sulfide Sputtering Target
- Chromium Telluride Sputtering Target
- Chromium Titanium Sputtering Target
- Chromium Trioxide Sputtering Targets
- Chromium Vanadium Sputtering Target
- Chromium Zirconium Oxide Sputtering Target
- Cobalt Chromium Aluminum Sputtering Target
- Cobalt Chromium Iron Sputtering Target
- Cobalt Chromium Molybdenum Alloy Sputtering Target
- Cobalt Chromium Sputtering Target
- Cobalt Chromium Tantalum Boron Sputtering Target
- Cobalt Chromium Tantalum Sputtering Target
- Cobalt Nickel Chromium Sputtering Target
- Copper Chromium Zirconium Alloy Sputtering Target
- Gallium Chromate Sputtering Target
- Iron Chromium Sputtering Target
- Lanthanum Chromite Sputtering Target
- Lanthanum Strontium Chromite Sputtering Target (LSC)
- Molybdenum Chromium Sputtering Target
- Nickel Chromium Aluminum Sputtering Target
- Nickel Chromium Aluminum Silicon Sputtering Target
- Nickel Chromium Silicon Sputtering Target
- Nickel Chromium Sputtering Target
- Strontium Chromate Sputtering Target
- Titanium Aluminum Carbide/Chromium Carbide Sputtering Target
- Titanium Aluminum Chromium Sputtering Target
- Titanium Chromium Sputtering Target
- Vanadium Chromium Sputtering Target
Isotopes
Chromium's hardness and high resistance to corrosion make it ideal for alloying and steel producing applications. Steel can be made highly resistant to corrosion and discoloration by the addition of chromium, forming stainless steel.
When chromium is added to glass or ceramic glazes, it produces a brilliant green color. Chromium is available as metal and compounds with purities from 99% to 99.999% (ACS grade to ultra-high purity). Elemental or metallic forms include pellets, rod, wire and granules for evaporation source material purposes. Chromium nanoparticles and nanopowders are also available. Chromium oxides are available in powder and dense pellet form for such uses as optical coating and thin film applications. Oxides tend to be insoluble. Chromium fluoride is another insoluble form for uses in which oxygen is undesirable such as metallurgy, chemical and physical vapor deposition and in some optical coatings. Chromium is also available in soluble forms including chlorides, nitrates and acetates. These compounds can be manufactured as solutions at specified stoichiometries.
Chromium Properties
Chromium is a Block D, Group 6, Period 4 element.
The number of electrons in each of Chromium's shells is 2, 8, 13, 1 and its electron configuration is [Ar] 3d5 4s1. The chromium atom has a radius of 128.pm and its Van der Waals radius is 200.pm. In its elemental form, CAS 7440-47-3,
chromium has a lustrous steel-gray appearance. Chromium is the hardest metal element in the periodic table. The most common source of chromium is chromite ore (FeCr2O4). Chromium was first discovered by Louis Nicolas Vauquelin in 1797. Due to its various colorful compounds, chromium was named after the Greek word 'chroma' meaning color.
General Properties
Symbol: | Cr |
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Atomic Number: | 24 |
Atomic Weight: | 51.9961 |
Element Category: | transition metal |
Group, Period, Block: | 6, 4, d |
Color: | silvery metallic/ silver-gray |
Other Names: | Chrom, Cromo, Krom, Crômio |
Physical Properties
Melting Point: | 1907 °C, 3465 °F, 2180 K |
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Boiling Point: | 2671 °C, 4840 °F, 2944 K |
Density: | 7.19 g/cm3; @ 20 °C |
Liquid Density @ Melting Point: | 6.3 g/cm3 |
Density @ 20°C: | 7.19 g/cm3 |
Density of Solid: | 7140 kg·m3 |
Specific Heat: | 0.46 kJ/kg/K |
Superconductivity Temperature: | N/A |
Triple Point: | N/A |
Critical Point: | N/A |
Heat of Fusion (kJ·mol-1): | 15.3 |
Heat of Vaporization (kJ·mol-1): | 341.8 |
Heat of Atomization (kJ·mol-1): | 394.51 |
Thermal Conductivity: | 93.9 W·m-1·K-1 |
Thermal Expansion: | (25 °C) 4.9 µm·m-1·K-1 |
Electrical Resistivity: | (20 °C) 125 nΩ·m |
Tensile Strength: | 282 MPa |
Molar Heat Capacity: | 23.35 J·mol-1·K-1 |
Young's Modulus: | 279 GPa |
Shear Modulus: | 115 GPa |
Bulk Modulus: | 160 GPa |
Poisson Ratio: | 0.21 |
Mohs Hardness: | 8.5 |
Vickers Hardness: | 1060 MN m-2 |
Brinell Hardness: | 1120 MN m-2 |
Speed of Sound: | (20 °C) 5940 m·s-1 |
Pauling Electronegativity: | 1.66 |
Sanderson Electronegativity: | 1.66 |
Allred Rochow Electronegativity: | 1.56 |
Mulliken-Jaffe Electronegativity: | N/A |
Allen Electronegativity: | N/A |
Pauling Electropositivity: | 2.34 |
Reflectivity (%): | N/A |
Refractive Index: | N/A |
Chemical Properties
Electrons: | 24 |
---|---|
Protons: | 24 |
Neutrons: | 28 |
Electron Configuration: | [Ar] 3d5 4s1 |
Atomic Radius: | 128 pm |
Atomic Radius, non-bonded (Å): | 2.06 |
Covalent Radius: | 139±5 pm |
Covalent Radius (Å): | 1.3 |
Van der Waals Radius: | 200 pm |
Oxidation States: | 6, 5, 4, 3, 2, 1, -1, -2 (strongly acidic oxide) |
Phase: | Solid |
Crystal Structure: | body-centered cubic |
Magnetic Ordering: | AFM |
Electron Affinity (kJ·mol-1) | 64.237 |
1st Ionization Energy: | 652.87 kJ·mol-1 |
2nd Ionization Energy: | 1590.64 kJ·mol-1 |
3rd Ionization Energy: | 2987.21 kJ·mol-1 |
Identifiers
CAS Number: | 7440-47-3 |
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EC Number: | 231-157-5 |
MDL Number: | MFCD00010944 |
Beilstein Number: | N/A |
SMILES Identifier: | [Cr] |
InChI Identifier: | InChI=1S/Cr |
InChI Key: | VYZAMTAEIAYCRO-UHFFFAOYSA-N |
PubChem CID: | 23976 |
ChemSpider ID: | 22412 |
Abundance
Earth - Total: | 4120 ppm |
---|---|
Mercury - Total: | 7180 ppm |
Venus - Total: | 4060 ppm |
Earth - Seawater (Oceans), ppb by weight: | 0.6 |
Earth - Seawater (Oceans), ppb by atoms: | 0.071 |
Earth - Crust (Crustal Rocks), ppb by weight: | 140000 |
Earth - Crust (Crustal Rocks), ppb by atoms: | 55000 |
Sun - Total, ppb by weight: | 20000 |
Sun - Total, ppb by atoms: | 400 |
Stream, ppb by weight: | 1 |
Stream, ppb by atoms: | 0.02 |
Meterorite (Carbonaceous), ppb by weight: | 3100000 |
Meterorite (Carbonaceous), ppb by atoms: | 1200000 |
Typical Human Body, ppb by weight: | 30 |
Typical Human Body, ppb by atom: | 4 |
Universe, ppb by weight: | 15000 |
Universe, ppb by atom: | 400 |
History
Discovered By: | Louis Nicolas Vauquelin |
---|---|
Discovery Date: | 1797 |
First Isolation: | Louis Nicolas Vauquelin (1798) |
Health, Safety & Transportation Information for Chromium
Although chromium metal is an essential trace element, hexavalent chromium (Cr(VI)) is especially toxic and carcinogenic to humans. Safety data for Chromium and its compounds can vary widely depending on the form. For potential hazard information, toxicity, and road, sea and air transportation limitations, such as DOT Hazard Class, DOT Number, EU Number, NFPA Health rating and RTECS Class, please see the specific material or compound referenced in the Products tab. The below information applies to elemental (metallic) Chromium.
Safety Data | |
---|---|
Signal Word | Warning |
Hazard Statements | H400 |
Hazard Codes | N/A |
Risk Codes | N/A |
Safety Precautions | N/A |
RTECS Number | GB4200000 |
Transport Information | N/A |
WGK Germany | N/A |
Globally Harmonized System of Classification and Labelling (GHS) | ![]() |
Review and Print SDS for Chromium Metal
SAFETY DATA SHEET
SECTION 1. IDENTIFICATION
Product Name: Chromium Metal
Product Number: All applicable American Elements product codes, e.g. CR-M-02, CR-M-03, CR-M-04, CR-M-05
CAS #: 7440-47-3
Relevant identified uses of the substance: Scientific research and development
Supplier details:
American Elements
1093 Broxton Ave. Suite 2000
Los Angeles, CA 90024
Tel: +1 310-208-0551
Fax: +1 310-208-0351
Emergency telephone number:
Domestic, North America +1 800-424-9300
International +1 703-527-3887
SECTION 2. HAZARDS IDENTIFICATION
Classification of the substance or mixture
Classification according to Regulation (EC) No 1272/2008
The substance is not classified as hazardous to health or the environment according to the CLP regulation.
Classification according to Directive 67/548/EEC or Directive 1999/45/EC
Not applicable
Information concerning particular hazards for human and environment:
No information known.
Hazards not otherwise classified
No information known.
Label elements
Labelling according to Regulation (EC) No 1272/2008
Not applicable
Hazard pictograms
Not applicable
Signal word
Not applicable
Hazard statements
Not applicable
WHMIS classification
Not controlled
Classification system
HMIS ratings (scale 0-4)
(Hazardous Materials Identification System)
HEALTH
FIRE
REACTIVITY
0
0
0
Health (acute effects) = 0
Flammability = 0
Physical Hazard = 0
Other hazards
Results of PBT and vPvB assessment
PBT:
Not applicable.
vPvB:
Not applicable.
SECTION 3. COMPOSITION/INFORMATION ON INGREDIENTS
Chemical characterization: Substances
CAS# Description:
7440-47-3 Chromium
Identification number(s):
EC number: 231-157-5
SECTION 4. FIRST AID MEASURES
Description of first aid measures
General information No special measures required.
After inhalation Seek medical treatment in case of complaints.
After skin contact Generally the product does not irritate the skin.
After eye contact
Rinse opened eye for several minutes under running water. If symptoms persist, consult a doctor.
After swallowing If symptoms persist consult doctor.
Information for doctor
Most important symptoms and effects, both acute and delayed
No further relevant information available.
Indication of any immediate medical attention and special treatment needed
No further relevant information available.
SECTION 5. FIREFIGHTING MEASURES
Extinguishing media
Suitable extinguishing agents Special powder for metal fires. Do not use water.
For safety reasons unsuitable extinguishing agents Water
Special hazards arising from the substance or mixture
In case of fire, the following can be released:
Toxic metal oxide fume
Advice for firefighters
Protective equipment: No special measures required.
SECTION 6. ACCIDENTAL RELEASE MEASURES
Personal precautions, protective equipment and emergency procedures Not required.
Environmental precautions:
Do not allow material to be released to the environment without proper governmental permits.
Methods and material for containment and cleaning up: Pick up mechanically.
Reference to other sections
See Section 7 for information on safe handling
See Section 8 for information on personal protection equipment.
See Section 13 for disposal information.
SECTION 7. HANDLING AND STORAGE
Handling
Precautions for safe handling
Keep container tightly sealed.
Store in cool, dry place in tightly closed containers.
Information about protection against explosions and fires:
No special measures required.
Conditions for safe storage, including any incompatibilities
Storage
Requirements to be met by storerooms and receptacles:
No special requirements.
Information about storage in one common storage facility:
No information known.
Further information about storage conditions:
Keep container tightly sealed.
Store in cool, dry conditions in well sealed containers.
Specific end use(s)
No further relevant information available.
SECTION 8. EXPOSURE CONTROLS/PERSONAL PROTECTION
Additional information about design of technical systems:
No further data; see section 7.
Control parameters
Components with limit values that require monitoring at the workplace:
7440-47-3 Chromium (100.0%)
PEL (USA) Long-term value: 1* 0.5** mg/m³
*metal;**inorganic compds., as Cr
REL (USA) Long-term value: 0.5* mg/m³
*metal+inorg.compds.as Cr;See Pocket Guide App. C
TLV (USA) Long-term value: 0.5 mg/m³
EL (Canada) Short-term value: C 0.1*** ppm
Long-term value: 0.5* 0.01** 0.025*** mg/m³
IARC1,ACGIH A1;*metal, i
norg.**insol.;**water-sol.
EV (Canada) Long-term value: 0.05 mg/m³
Additional information:
No data
Exposure controls
Personal protective equipment
General protective and hygienic measures
The usual precautionary measures for handling chemicals should be followed.
Maintain an ergonomically appropriate working environment.
Breathing equipment:
Not required.
Protection of hands:
Not required.
Penetration time of glove material (in minutes)
Not determined
Eye protection:
Safety glasses
Body protection:
Protective work clothing.
SECTION 9. PHYSICAL AND CHEMICAL PROPERTIES
Information on basic physical and chemical properties
General Information
Appearance:
Form: Solid in various forms
Color: Grey
Odor: Odorless
Odor threshold: Not determined.
pH-value: Not applicable.
Change in condition
Melting point/Melting range: 1907 °C (3465 °F)
Boiling point/Boiling range: 2671 °C (4840 °F)
Sublimation temperature / start: Not determined
Flammability (solid, gaseous)
Not determined.
Ignition temperature: Not determined
Decomposition temperature: Not determined
Auto igniting: Not determined.
Danger of explosion: Not determined.
Explosion limits:
Lower: Not determined
Upper: Not determined
Vapor pressure at 20 °C (68 °F): 0 hPa
Density at 20 °C (68 °F): 7.19 g/cm³ (60.001 lbs/gal)
Bulk density at 20 °C (68 °F): 3300 kg/m³
Relative density
Not determined.
Vapor density
Not applicable.
Evaporation rate
Not applicable.
Solubility in / Miscibility with Water: Insoluble
Partition coefficient (n-octanol/water): Not determined.
Viscosity:
dynamic: Not applicable.
kinematic: Not applicable.
Other information
No further relevant information available.
SECTION 10. STABILITY AND REACTIVITY
Reactivity
No information known
Chemical stability
Stable under recommended storage conditions.
Thermal decomposition / conditions to be avoided:
Decomposition will not occur if used and stored according to specifications.
Possibility of hazardous reactions
No dangerous reactions known
Conditions to avoid
No further relevant information available.
Incompatible materials:
No information known.
Hazardous decomposition products:
Toxic metal oxide fume
SECTION 11. TOXICOLOGICAL INFORMATION
Information on toxicological effects
Acute toxicity:
The Registry of Toxic Effects of Chemical Substances (RTECS) contains acute toxicity data for components in this product.
LD/LC50 values that are relevant for classification:
No data
Skin irritation or corrosion:
Generally the product does not irritate the skin.
Eye irritation or corrosion:
May cause irritation
Sensitization:
No sensitizing effects known.
Germ cell mutagenicity:
The Registry of Toxic Effects of Chemical Substances (RTECS) contains mutation data for this substance.
Carcinogenicity:
IARC-3: Not classifiable as to carcinogenicity to humans.
ACGIH A4: Not classifiable as a human carcinogen: Inadequate data on which to classify the agent in terms of its carcinogenicity in humans and/or animals.
(inhalation) EPA-A: human carcinogen: sufficient evidence from epidemiologic studies to support a causal association between exposure and cancer.
(inhalation) EPA-K: Known human carcinogens.
(oral) EPA-D: Not classifiable as to human carcinogenicity: inadequate human and animal
evidence of carcinogenicity or no data are available.
(oral) EPA-CBD: Carginogenic potential cannot be determined.
The Registry of Toxic Effects of Chemical Substances (RTECS) contains tumorigenic and/or carcinogenic and/or neoplastic data for this substance.
Reproductive toxicity:
The Registry of Toxic Effects of Chemical Substances (RTECS) contains reproductive data for this substance.
Specific target organ system toxicity - repeated exposure:
No effects known.
Specific target organ system toxicity - single exposure:
No effects known.
Aspiration hazard:
No effects known.
Subacute to chronic toxicity:
No effects known.
Additional toxicological information:
To the best of our knowledge the acute and chronic toxicity of this substance is not fully known.
SECTION 12. ECOLOGICAL INFORMATION
Toxicity
Aquatic toxicity:
No further relevant information available.
Persistence and degradability
No further relevant information available.
Bioaccumulative potential
No further relevant information available.
Mobility in soil
No further relevant information available.
Additional ecological information:
General notes:
Do not allow material to be released to the environment without proper governmental permits.
Do not allow undiluted product or large quantities to reach ground water, water course or sewage system.
Avoid transfer into the environment.
Results of PBT and vPvB assessment
PBT:
Not applicable.
vPvB:
Not applicable.
Other adverse effects
No further relevant information available.
SECTION 13. DISPOSAL CONSIDERATIONS
Waste treatment methods
Recommendation
Consult state, local or national regulations to ensure proper disposal.
Uncleaned packagings:
Recommendation:
Disposal must be made according to official regulations.
SECTION 14. TRANSPORT INFORMATION
UN-Number
DOT, ADN, IMDG, IATA
Not applicable
UN proper shipping name
DOT, ADN, IMDG, IATA
Not applicable
Transport hazard class(es)
DOT, ADR, ADN, IMDG, IATA
Class
Not applicable
Packing group
DOT, IMDG, IATA
Not applicable
Environmental hazards:
Not applicable.
Special precautions for user
Not applicable.
Transport in bulk according to Annex II of MARPOL73/78 and the IBC Code
Not applicable.
Transport/Additional information:
DOT
Marine Pollutant (DOT):
No
SECTION 15. REGULATORY INFORMATION
Safety, health and environmental regulations/legislation specific for the substance or mixture
National regulations
All components of this product are listed in the U.S. Environmental Protection Agency Toxic Substances Control Act Chemical substance Inventory.
All components of this product are listed on the Canadian Domestic Substances List (DSL).
SARA Section 313 (specific toxic chemical listings)
7440-47-3 Chromium
California Proposition 65
Prop 65 - Chemicals known to cause cancer
Substance is not listed.
Prop 65 - Developmental toxicity
Substance is not listed.
Prop 65 - Developmental toxicity, female
Substance is not listed.
Prop 65 - Developmental toxicity, male
Substance is not listed.
Information about limitation of use:
For use only by technically qualified individuals.
Other regulations, limitations and prohibitive regulations
Substance of Very High Concern (SVHC) according to the REACH Regulations (EC) No. 1907/2006.
Substance is not listed.
The conditions of restrictions according to Article 67 and Annex XVII of the Regulation (EC) No 1907/2006 (REACH) for the manufacturing, placing on the market and use must be observed.
Substance is not listed.
Annex XIV of the REACH Regulations (requiring Authorisation for use)
Substance is not listed.
REACH - Pre-registered substances
Substance is listed.
Chemical safety assessment:
A Chemical Safety Assessment has not been carried out.
16. OTHER INFORMATION
Safety Data Sheet according to Regulation (EC) No. 1907/2006 (REACH). The above information is believed to be correct but does not purport to be all inclusive and shall be used only as a guide. The information in this document is based on the present state of our knowledge and is applicable to the product with regard to appropriate safety precautions. It does not represent any guarantee of the properties of the product. American Elements shall not be held liable for any damage resulting from handling or from contact with the above product. See reverse side of invoice or packing slip for additional terms and conditions of sale. COPYRIGHT 1997-2016 AMERICAN ELEMENTS. LICENSED GRANTED TO MAKE UNLIMITED PAPER COPIES FOR INTERNAL USE ONLY.
Chromium Isotopes
Naturally occurring chromium (Cr) has four stable isotopes; 50Cr, 52Cr, 53Cr, and 54Cr. 52Cr is the most abundant (83.79%). 50Cr decays by ß+ß+ to 50Ti with a half-life of (more than) 1.8x1017 years.
Nuclide | Isotopic Mass | Half-Life | Mode of Decay | Nuclear Spin | Magnetic Moment | Binding Energy (MeV) | Natural Abundance (% by atom) |
---|---|---|---|---|---|---|---|
42Cr | 42.00643(32)# | 14(3) ms [13(+4-2) ms] | ß+ to 42V; ß+ + 2p to 40Ti | (3/2+) | N/A | 306.79 | - |
43Cr | 42.99771(24)# | 21.6(7) ms | ß+ to 43V; ß+ + p to 42Ti; ß+ + 2p to 41Sc; ß+ + a to 39Sc | 0+ | N/A | 323.25 | - |
44Cr | 43.98555(5)# | 54(4) ms [53(+4-3) ms] | ß+ to 44V; ß+ + p to 43Ti | 7/2-# | N/A | 342.51 | - |
45Cr | 44.97964(54) | 50(6) ms | ß+ to 45V; ß+ + p to 44Ti | 0+ | N/A | 356.18 | - |
46Cr | 45.968359(21) | 0.26(6) s | ß+ to 46V | 3/2- | N/A | 374.5 | - |
47Cr | 46.962900(15) | 500(15) ms | ß+ to 47V | 0+ | N/A | 388.17 | - |
48Cr | 47.954032(8) | 21.56(3) h | EC to 48V | 5/2- | N/A | 403.7 | - |
49Cr | 48.9513357(26) | 42.3(1) min | EC to 49V | 0+ | 0.476 | 414.58 | - |
50Cr | 49.9460442(11) | Observationally Stable | - | 7/2- | N/A | 403.7 | 4.345 |
51Cr | 50.9447674(11) | 27.7025(24) d | EC to 51V | 0+ | -0.934 | 414.58 | - |
52Cr | 51.9405075(8) | STABLE | - | 3/2- | N/A | 427.31 | 83.789 |
53Cr | 52.9406494(8) | STABLE | - | 0+ | -0.47454 | 437.26 | 9.501 |
54Cr | 53.9388804(8) | STABLE | - | 3/2- | N/A | 449.06 | 2.365 |
55Cr | 54.9408397(8) | 3.497(3) min | ß- to 55Mn | 0+ | N/A | 457.14 | - |
56Cr | 55.9406531(20) | 5.94(10) min | ß- to 56Mn | (3/2-) | N/A | 467.08 | - |
57Cr | 56.943613(2) | 21.1(10) s | ß- to 57Mn | 0+ | N/A | 486.66 | - |
58Cr | 57.94435(22) | 7.0(3) s | ß- to 58Mn | 5/2-# | N/A | 493.81 | - |
59Cr | 58.94859(26) | 460(50) ms | ß- to 59Mn | 0+ | N/A | 498.16 | - |
60Cr | 59.95008(23) | 560(60) ms | ß- to 60Mn | 5/2-# | N/A | 504.37 | - |
61Cr | 60.95472(27) | 261(15) ms | ß- to 61Mn; ß- + n to 60Mn | 0+ | N/A | 508.73 | - |
62Cr | 61.95661(36) | 199(9) ms | ß- to 62Mn; ß- + n to 61Mn | (1/2-)# | N/A | 514.94 | - |
63Cr | 62.96186(32)# | 129(2) ms | ß- to 63Mn; ß- + n to 62Mn | 0+ | N/A | 518.36 | - |
64Cr | 63.96441(43)# | 43(1) ms | ß- to 64Mn | (1/2-)# | N/A | 523.65 | - |
65Cr | 64.97016(54)# | 27(3) ms | ß- to 65Mn | 0+ | N/A | 526.14 | - |
66Cr | 65.97338(64)# | 10(6) ms | ß- to 66Mn | 1/2-# | N/A | 531.42 | - |
67Cr | 66.97955(75)# | 10# ms [>300 ns] | ß- to 67Mn | 1/2 | N/A | 533.91 | - |